The effect and feasibility of peat soil environment (PSE) simulation pose a difficult problem for geotechnical environmental engineering. In this study, the actual content of humic group (HG) in peat soil of Dianchi Lake is determined, and the method of adding humic acid (HA) reagent into cohesive soil and soaking it in fulvic acid (FA) solution is used to simulate PSE of Dianchi Lake. By comparing the HG content of test samples and natural peat soil, the effect and feasibility of simulation test are studied. And the effects of HG on microstructure and material composition of PSE are analyzed by scanning electron microscopy (SEM) and X‐ray diffraction (XRD) tests. The test results show that the content of HG and its components of PSE in seven sites of Dianchi Lake are quite different. The simulation method used in this study can simulate the PSE with different HA and FA contents, but the simulation method of soaking samples in FA solution cannot reach the actual effect. The SEM test confirm that the pore size and pore connectivity will increase with the HA reagent. However, FA is wrapped on the skeleton of soil through adsorption and fills some pores, which reduces the pore diameter and weakens pore connectivity. The XRD test shows that both HA and FA can reduce the diffraction peak of main substances in the samples, but not including SiO2. The reason is that HG and cohesive soil particles undergo coordination exchange and ion exchange; free HG combines with cohesive soil particles and transforms into bound HG, forming an organic‐inorganic complex PSE.
The disposal of soil containing humic acid (HA) poses an increasingly difficult problem for geotechnical environmental engineering. In this study, the unconfined compressive strength (UCS) test of cement‐soil with different HA contents is conducted to analyze the effect of HA on the strength of cement‐soil. Mercury intrusion porosimetry (MIP), scanning electron microscopy (SEM), and X‐ray diffraction (XRD) experiments reveal the effective mechanism of HA on the strength of cement‐soil from the microscopic level. The results show that the strength of cement‐soil decreases gradually with the increase of HA content. The failure mode of cement‐soil slightly changed from brittle failure to plastic failure. The microscopic test shows that the incorporation of HA will lead to the apparent enlargement of the pores in the cement‐soil. The large pores in the sample increase, the small micropores decrease, and the structure tends to be loose and overhead. The increased HA content added will significantly reduce the cement hydration products and destroy the cementation of the hydration products.
The peat soil in the Dianchi Lake area of Yunnan, China, is widely distributed, bringing many problems to engineering. The peat soil foundation is usually treated by the cement mixing method, and the reinforcement effect of cemented soil is mainly affected by humic acid (HA). Ultra-fine cement (UFC) can improve cement performance and reduce cement consumption, decreasing CO2 emissions and the impact of human activities on the environment. Simulated peat soils in different environments are prepared with HA reagent and cohesive soil, reinforced by composite cement curing agent mixed with ultrafine cement (UFC). The relationship among the UFC proportion, HA reagent content, soaking time, and sample strength was studied. The unconfined compressive strength test (UCS), scanning electron microscope (SEM), and PCAS microscopic quantitative test techniques were used to explore the mechanism of the effect of UFC on the strength of HA-containing cemented soil. The increasing UFC proportion in the composite cement curing agent gradually increased HA-containing cemented soil’s strength. UFC significantly reduced the percentage of macropores in HA-containing cemented soil and made the microstructure denser. The HA-containing cemented soil’s qu increased the most when the UFC proportion increased from 0% to 10%. The solidification effect of the composite cement curing agent mixed with UFC was always stronger than that of OPC. The composite cement curing agent with a UFC proportion of 10% is practical. Cement is still an important building material in the current construction industry, and UFC provides a new method for reducing environmental impact in engineering construction.
Peat soil is widely distributed in the Dianchi Lake area of Yunnan, and the effect of the cement deep-mixing method on peat soil foundation is mainly affected by humic acid (HA). In this paper, a composite cement curing agent is formed by adding different proportions of ultra-fine cement (UFC) to ordinary Portland cement (OPC) and used to cure the HA-containing cohesive soil. Mercury intrusion porosimetry (MIP), scanning electron microscopy (SEM), and X-ray powder diffraction (XRD) are used to study the influence mechanism of UFC on the micropore structure of HA-containing cemented soil. The unconfined compressive strength test (UCS) is used to verify it. MIP, SEM, and XRD results show that UFC can significantly improve the microscopic pore structure of the samples. The hydration reaction rate of cement increases with the increase in the proportion of UFC, and the generated hydration products can fill the pores of the samples. The filling effect of hydration products on macropores is enhanced, and the pores change from fibrous filling to cemented filling. The enhanced cementation of the hydration products improved the loose and overhead structure inside the sample. Enhancing the cementation of hydration products improves the loose and overhead structure inside the sample and the integrity of cemented soil. UCS verified that the increase in the UFC proportion increases the HA-containing cemented soil strength. It achieves the purpose of reducing the amount of cement when curing peat soil foundations and supports reducing carbon emissions in practical projects.
2 November 2022 in Advances in Materials Science and Engineering
The organic soil is widely distributed around Dianchi Lake in Kunming, which is rich in the humic group (HG). In order to explore the effect of HG on the strength development of organic soil, this paper adopts the method of adding humic acid (HA) reagent into the undisturbed cohesive soil (blending method) and soaking it in fulvic acid (FA) solution (steeping method) to simulate the organic soil. Then, the effect of HG on soil is analyzed by the unconfined compressive strength (UCS) and the scanning electron microscope (SEM) tests. The UCS test shows that HA can significantly reduce the UCS of the samples, and it continues to decrease with the increase of the HA reagent content. FA can substantially enhance the UCS of the samples, which continues to increase with the concentration of FA solution (decreasing the pH value). Under each HG condition, the steeping of FA can significantly increase the UCS of the sample when the content of the HA reagent is less than 10%, and the growth rate of the UCS decreases when it is greater than 10%. With the increase of steeping age, the UCS of the 5% HA samples continued to increase and gradually became stable, and when the content of the HA reagent is more than 5%, the UCS curve first increases and then decreases. The SEM test shows that adding HA reagent can significantly increase the pore size, improve the connectivity between the pores, and weaken the connection of the soil structure. The steeping of FA can reduce the pore size, weaken the connectivity between the pores, and strengthen the connection of the sample structure.