Incorporating nanoparticles (NPs) into the selective layer of thin-film composite (TFC) membranes is a common approach to improve the performance of the resulting thin-film nanocomposite (TFN) membranes. The main challenge in this approach is the leaching out of NPs during membrane operation. Halloysite nanotubes (HNTs) modified with the first generation of poly(amidoamine) (PAMAM) dendrimers (G1) have shown excellent stability in the PA layer of TFN reverse-osmosis (RO) membranes. This study explores, for the first time, using these NPs to improve the properties of TFN nanofiltration (NF) membranes. Membrane performance was evaluated in a cross-flow nanofiltration (NF) system using 3000 ppm aqueous solutions of MgCl₂, Na₂SO₄ and NaCl, respectively, as feed at 10 bar and ambient temperature. All membranes showed high rejection of Na₂SO₄ (around 97–98%) and low NaCl rejection, with the corresponding water fluxes greater than 100 L m⁻² h⁻¹. The rejection of MgCl₂ (ranging from 82 to 90%) was less than that for Na₂SO₄. However, our values are much greater than those reported in the literature for other TFN membranes. The remarkable rejection of MgCl₂ is attributed to positively charged HNT-G1 nanoparticles incorporated in the selective polyamide (PA) layer of the TFN membranes.

The application of nanofiltration (NF) membranes in the forward osmosis (FO) process to remove heavy metal ions from wastewater is an emerging concept. Unlike NF, FO does not require an external driving force. Although the product, a dilute draw solution, must further be processed by NF to produce pure water and reconcentrate a draw solution, the feed to that NF process is “clean”, which minimizes membrane fouling. This paper examines the role of Cu²⁺ and Pb²⁺ in the feed solution on the water and the reverse solute fluxes in FO process using novel thin film nanocomposite (TFN) NF membranes. The TFN membranes were fabricated by in situ interfacial polymerization of piperazine (PIP) and 1,3,5-benzenetricarbonyl trichloride (TMC) containing different amounts of dispersed halloysite nanotubes (HNTs) nanoparticles functionalized with the first generation of poly(amidoamine) (PAMAM) dendrimers. The presence of Cu²⁺ and Pb²⁺ in the feed solution decreased the reverse flux of MgCl₂ by at least 2.5 times compared to the experiments with pure water as a feed. Simultaneously, the water flux also increased. The corresponding rejections of Cu²⁺ and Pb²⁺ in the FO process ranged from 94.5% to 98.1%.

Forward osmosis (FO) is an emerging technology for seawater and brackish desalination, wastewater treatment, and other applications, such as food processing, power generation, and protein and pharmaceutical enrichment. However, choosing a draw solute (DS) that provides an appropriate driving force and, at the same time, is easy to recover, is challenging. In this study, water-soluble poly(styrene sulfonate) (PSS) was modified by a high-electrical-conductivity 3,4-ethylenedioxythiophene (EDOT) monomer to fabricate a novel draw solute (mPSS). FO tests with the CTA membrane in the active layer facing the feed solution (AL-FS) orientation, using a 50 mS/cm aqueous solution of synthesized solute and distilled water as a feed solution exhibited a water flux of 4.2 L h⁻¹ m⁻² and a corresponding reverse solute flux of 0.19 g h⁻¹ m⁻². The FO tests with the same membrane, using a 50 mS/cm NaCl control draw solution, yielded a lower water flux of 3.6 L h⁻¹ m⁻² and a reverse solute flux of 4.13 g h⁻¹ m⁻², which was more than one order of magnitude greater. More importantly, the synthesized draw solute was easily regenerated using a commercial ultrafiltration membrane (PS35), which showed over 96% rejection.

Novel TFN membranes were examined for the removal of heavy metals (Cu and Pb) from synthetic wastewater in forward osmosis (FO) experiments using MgCl2 as a draw solute. The TFN membranes were fabricated on top of a commercial PS35 ultrafiltration membrane by in-situ interfacial polymerization of piperazine (PIP) and 1,3,5-benzenetricarbonyl trichloride (TMC) containing different amounts of dispersed functionalized halloysite nanotubes (HNTs) nanoparticles. The HNTs nanoparticles were functionalized with the first generation of poly(amidoamine) (PAMAM) dendrimers. The TFN and the control TFC membranes showed rejections of Cu2+ and Pb2+, ranging from 94.5% to 98.1%. The presence of heavy metal in the feed solution enhanced the FO performance of all membranes. In particular, the reverse flux of MgCl2 decreased at least 2.5 times compared to the experiments with pure water as a feed. Simultaneously, the water flux also increased. The improved FO performance of the membranes in the presence of heavy metal ions is attributed to their adsorption by the membranes. The adsorption of heavy metals was confirmed by a decrease in the negativity of zeta potential and the results from inductively coupled plasma mass spectrometry (ICP-MS) of the membranes after the FO experiments.