The treatment of oily wastewater has become a serious environmental challenge, for which graphene oxide has emerged as a promising material in solving the problem. The ever-growing utilization of graphene oxide (GO) in the treatment of oily wastewater necessitates a constant review. This review article employs a comprehensive literature survey methodology, systematically examining peer-reviewed articles, focusing on, but not entirely limited to, the last five years. Major databases such as EBSCOhost, Scopus, ScienceDirect, Web of Science and Google Scholar were searched using specific keywords related to GO and oily wastewater treatment. The inclusion criteria focused on studies that specifically address the application, efficiency, and mechanisms of GO in treating oily wastewater. The data extracted from these sources were then synthesized to highlight the most important developments, challenges, and prospects in this field. As far as oily wastewater treatment is concerned, the majority of the studies revolve around the use of GO in mitigating fouling in membrane processes, improving the stability, capacity and reusability of sorbents, and enhancing photodegradation by minimizing charge recombination.

Although ultrafiltration is a reliable method for separating oily wastewater, the process is limited by problems of low flux and membrane fouling. In this study, for the first time, commercial TiO₂/ZrO₂ ceramic membranes modified with silver-functionalized copper oxide (Ag-CuO) nanoparticles are reported for the improved separation performance of emulsified oil. Ag-CuO nanoparticles were synthesized via hydrothermal technique and dip-coated onto commercial membranes at varying concentrations (0.1, 0.5, and 1.0 wt.%). The prepared membranes were further examined to understand the improvements in oil-water separation due to Ag-CuO coating. All modified ceramic membranes exhibited higher hydrophilicity and decreased porosity. Additionally, the permeate flux, oil rejection, and antifouling performance of the Ag-CuO-coated membranes were more significantly improved than the pristine commercial membrane. The 0.5 wt.% modified membrane exhibited a 30% higher water flux (303.63 L m⁻² h⁻¹) and better oil rejection efficiency (97.8%) for oil/water separation among the modified membranes. After several separation cycles, the 0.5 wt.% Ag-CuO-modified membranes showed a constant permeate flux with an excellent oil rejection of >95% compared with the unmodified membrane. Moreover, the corrosion resistance of the coated membrane against acid, alkali, actual seawater, and oily wastewater was remarkable. Thus, the Ag-CuO-modified ceramic membranes are promising for oil separation applications due to their high flux, enhanced oil rejection, better antifouling characteristics, and good stability.

Rapid industrialization and the accompanying generation of significant amounts of oily wastewater pose major environmental challenges, which necessitate efficient treatment technologies. Kaolin-based membranes have emerged as a promising option due to their availability, affordability, and effective filtration performance. This review comprehensively analyzes the potential of kaolin for the treatment of oily wastewater. The focus is on the main manufacturing methods such as uniaxial pressing, slip casting, tape casting, phase inversion, and extrusion, as well as modifications that improve the structural integrity of the membrane, and its surface wettability to enhance separation performance. In addition, characterization techniques to evaluate membrane properties such as mechanical strength, thermal and chemical stability, antifouling behavior etc. are discussed. Basically, kaolin can be used as a supporting substrate, as a primary separation layer or as an additive in non-kaolin membranes. In evaluating the oil-water separation performance of kaolin-based membranes, this review highlights important metrics such as oil separation rate, flux, flux recovery, antifouling behavior, and resistance to harsh physical and chemical environments. Articles selected for the review were retrieved from major databases such as EBSCOhost, Scopus, ScienceDirect, Web of Science, and Google Scholar using relevant keywords. Based on the data from these studies, the main advances, challenges, and prospects are highlighted. Although still in the early stages of commercial application, kaolin membranes show significant potential to improve filtration efficiency, mechanical and chemical resistance, and reduce operating costs in industrial oily wastewater treatment systems.

This study investigates the effects of NaCl activation on the structural and chemical properties of kaolin for the adsorption of Zn²⁺ from solution. Kaolin was treated with NaCl solution at varying concentrations (0.5, 1.0, 2.0, and 4.0 M), and ultrasonication was used as a means of agitation. Scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), and dynamic light scattering (DLS) were employed to characterize the physical and chemical effects of the NaCl activation and its subsequent influence on the kaolin’s heavy metal removal efficiency. The kaolin activated with 0.5 M NaCl solution yielded the optimal performance with a 13% increase in Zn²⁺ removal compared to the unmodified clay. The adsorption data best matched the pseudo-second-order kinetic model and the Langmuir isotherm. This indicates a monolayer adsorption on a homogeneous surface, with chemisorption as the dominant adsorption mechanism. Thermodynamic analysis also revealed that the adsorption process was endothermic and spontaneous. Furthermore, NaCl activation slightly enhanced the microstructural properties of the kaolin and moderated the surface charge, creating a more favorable electrostatic environment for improved heavy metal ion adsorption. The findings further highlight the potential of NaCl activation to introduce exchangeable Na⁺ onto the kaolin surface in a pH-neutral environment and promise a clean, mechanistically clear, and practical route for ion exchange with heavy metals such as Zn²⁺.