At present, the common protection technology of power-transmission and transformation equipment is mainly coating protection and hot-dip zinc protection. However, due to the low adhesion of epoxy zinc-rich coating, and the poor compatibility with top paint, environmental pollution, complex processing, high energy consumption and other defects of the hot-dip zinc process, its development is limited. In view of the above deficiencies, new anti-corrosion coating materials and processes were investigated in this study. Zinc coatings and Al-Zn coatings were prepared on the C45 steel matrix by hot-spraying and cold-spraying processes. The macro appearance, micromorphology and phase composition analysis of the coatings were evaluated. The adhesion of the coating to the substrate after the salt-spray test was tested. The results showed that the hot dip zinc coating and hot spray zinc coating had obvious cracking after the salt-spray test. The surface structure of cold-sprayed Al-Zn coating was relatively dense after the salt-spray test. The critical load of the cold-sprayed Al-Zn coating after the salt-spray test was higher than that of the other two coatings. The corrosion resistance to salt spray of cold-sprayed Al-Zn coating was demonstrated to be better than the hot-dip zinc coating, and thus has great application prospects.
The measurement of bolt preload by using ultrasound can be accurate, convenient, and can realize the real-time monitoring of the change in the residual axial stress of a bolt during use. In order to realize the ultrasonic measurement of bolt preload, the use of zinc oxide (ZnO) piezoelectric thin-film material as an ultrasonic transducer material to stimulate an ultrasonic signal on the bolt is a feasible solution. In this paper, we choose to use RF magnetron sputtering technology to prepare ZnO piezoelectric thin-film materials and study the effects of sputtering power and target substrate distance on the structure and ultrasonic properties of ZnO piezoelectric thin films during the preparation process, in order to lay the foundation for realizing the application of ZnO piezoelectric thin films in the field of bolt preload measurement. The experimental results show that too-large sputtering power or too-small target substrate distance will result in the particles having too much kinetic energy during sputtering and exhibiting a structure of multiorientation growth, which excites ultrasonic longitudinal–transverse waves. A sputtering power of 600 W, sputtering time of 4 h, and target substrate distance of 100 mm are ideal experimental parameters for a ZnO piezoelectric thin-film material to be excited by an ultrasonic longitudinal wave signal, and its ideal operating frequency is 41 MHZ. These research results of bolt stress detection demonstrate good application prospects.
High-entropy nitride AlCrNbSiTiN coatings were deposited by RF magnetron sputtering at different bias voltages. The structure, mechanical properties and water vapor corrosion resistance of the coatings were systematically studied. The coatings exhibit a face-centered cubic (FCC) structure, while achieving a hardness up to 35.8 GPa. The main wear mechanisms of the coatings are adhesive wear and oxidation wear. After 200 h of water vapor corrosion, the content of O in the coatings is 4.30 at.%.
By introducing oxygen doping, the structure of an AlCrNbSiTiN coating was optimized, and its high-temperature oxidation resistance was improved. As the oxygen content incorporated increases, the coating changes from an FCC structure to an amorphous or spinel structure. Meanwhile, stress relaxation occurred, and the hardness of the coating dropped to 12 gpa. Oxygen-doped coatings exhibit excellent oxidation resistance; this is especially the case for oxidized coatings, whose structure remains stable up to 900 °C in an oxidizing environment.
Multi-principal element nitrides have great application potential in protective coatings. However, the investigation of the oxidation and corrosion resistance of multi-principal element nitride coatings is still insufficient. The synthesis and high-temperature performance of AlCrNbSiTiN multi-principal element nitride coatings fabricated through optimized arc ion plating (AIP) were explored. Leveraging the high ionization efficiency and ion kinetic energy characteristic of AIP, coatings with significantly fewer internal defects were obtained. These coatings demonstrate superior mechanical properties, including a maximum hardness of 36.5 GPa and critical crack propagation resistance (CPR) values approaching 2000 N2. Optimal coatings exhibited exceptional water vapor corrosion resistance (5.15 at% O after 200 h). The coatings prepared at −150 V had the optimal corrosion resistance, with the coating resistance and corrosion current density being 1.68 × 104 Ω·cm2 and 0.79 μA·cm−2, respectively. AlCrNbSiTiN coatings produced under these optimized AIP conditions exhibit remarkably high-temperature oxidation, highlighting their potential for use in demanding engineering applications.
The ZnO piezoelectric coatings were deposited on the surface of 15CrMo steels by magnetron sputtering to directly excite the ultrasonic signal, effectively solving the coupling problem between the traditional probe and the pipe surface. The microstructure, mechanical properties, and ultrasonic longitudinal wave velocity of the aged samples were carried out systematically. The spheroidization grade of pearlite, evolution of carbide morphology, hardness, strength, and ultrasonic wave velocity were systematically analyzed. As the degree of aging intensifies, the material undergoes significant pearlite spheroidization and carbide coarsening. The Vickers hardness drops from 158 HV in the original state to 134.2 HV, and the yield strength and tensile strength decrease by 22.7% and 17.9%, respectively. The ultrasonic longitudinal wave velocity shows a monotonically upward trend with the increase in spheroidization grade, increasing from 5925.6 m/s in the original state to 5976 m/s at the highest spheroidization grade.