In the light of the ever increasing dangers of global warming, the efforts to reduce energy consumption by radiative cooling techniques have been designed, but are inefficient under strong sunlight during the daytime. With the advent of metamaterials and their selective control over optical properties, radiative cooling under direct sunlight is now possible. The key principles of metamaterial-based radiative cooling are: almost perfect reflection in the visible and near-infrared spectrum (0.3–3 µm) and high thermal emission in the infrared atmospheric window region (8–13 µm). Based on these two basic principles, studies have been conducted using various materials and structures to find the most efficient radiative cooling system. In this review, we analyze the materials and structures being used for radiative cooling, and suggest the future perspectives as a substitute in the current cooling industry.
Sustainable energies from weather are the most ubiquitous and non-depleted resources. However, existing devices exploiting weather-dependent energies are sensitive to weather conditions and geographical locations, making their universal applicability challenging. Herein, we propose an all-weather sustainable glass surface integrating a triboelectric nanogenerator and radiative cooler, which serves as a sustainable device, harvesting energy from raindrops and saving energy on sunny days. By systematically designing transparent, high-performance triboelectric layers, functioning as thermal emitters simultaneously, particularly compatible with radiative cooling components optimized with an evolutionary algorithm, our proposed device achieves optimal performance for all-weather-dependent energies. We generate 248.28 Wm−2 from a single droplet with an energy conversion ratio of 2.5%. Moreover, the inner temperature is cooled down by a maximum of 24.1 °C compared to pristine glass. Notably, as the proposed device is realized to provide high transparency up to 80% in the visible range, we are confident that our proposed device can be applied to versatile applications.
Chirality, the absence of mirror symmetry, is predominant in nature. The chiral nature of the electromagnetic field behaves differently with chiral matter for left circularly polarized and right circularly polarized light. The chiroptical behavior in the sensing of naturally occurring chiral objects is weak, and improving the chiroptical response enhances the chiral sensing platform. This review covers the fundamental concepts of chiral metasurfaces and various types of single- and multi-layered chiral metasurfaces. In addition, we discuss tunable and deep-learning-based chiral metasurfaces. Tunability is achieved by manipulating the meta-atom’s property in response to external stimuli for applications such as optical modulation, chiral photonics, advanced sensing, and adaptive optics. Deep-learning modeling techniques, such as CNNs and GANs, offer efficient learning of the complex relationships in data, enabling the optimization and accurate prediction of chiral metasurface properties. The challenges in the design and fabrication of chiral metasurface include achieving broadband performance and scalability and addressing material limitations. Chiral metasurface performance is evaluated by optical rotation, circular dichroism enhancement, and tunability, which are quantified through the spectroscopic measurement of circular dichroism and optical rotation. Chiral metasurface progress enables applications, including metaholography, metalenses, and chiral sensing. Chiral sensing improves the detection of pharmaceuticals and biomolecules, increasing the sensitivity and accuracy of analytical diagnostics.
Generating colors by employing metallic nanostructures has attracted intensive scientific attention recently, because one can easily realize higher spatial resolution and highly robust colors compared to conventional pigment. However, since the scattering spectra and thereby the resultant colors are determined by the nanostructure geometries, only one fixed color can be produced by one design and a whole new sample is required to generate a different color. In this paper, we demonstrate active metasurface, which shows a range of colors dependent on incident polarization by selectively exciting three different plasmonic nanorods. The metasurface, which does not include any tunable materials or external stimuli, will be beneficial in real-life applications especially in the display applications.