The unique photonic effect of self-assembled metal nanoparticles is widely used in many applications. In this article, we prepared self-assembled gold nanorod (GNR) vertical arrays substrate by an evaporation method and found that the morphology of the substrate can be effectively regulated by changing the immersion time in the target molecules solution to obtain different Raman enhancement effects. We separately calculated the local electromagnetic field of the GNR vertical arrays and disorder substrate by the finite element method (FEM), which was consistent with the experimental results. Based on optimal soaking time, the sensitivity, reproducibility, and stability of substrates were separately studied. The experimental results show that the GNR vertical arrays can detect Rhodamine 6G (Rh6G) at concentrations as low as 10−11 M and exhibit good reproducibility and stability due to local electromagnetic (EM) field enhancement caused by the coupling of adjacent nanorods. Thus, our work can demonstrate that the substrate has excellent surface-enhanced Raman scattering (SERS) activity and the obtained GNR vertical arrays have great potential for biosensor and biodetection.

Surface-enhanced Raman scattering (SERS) is recognized as one of the most favored techniques for enhancing Raman signals. The morphology of the SERS substrate profoundly affects molecular Raman spectra. This study aimed to construct a ring-mounted nanostructured substrate via liquid–liquid two-phase self-assembly incorporated with anodic aluminum oxide (AAO) membrane transfer techniques. High-density nanoparticles (NPs) assembled on AAO membranes were ascribed to reduce the diameters of the nanopores, with Au–Ag alloy NPs to regulate the dielectric constant so as to reveal the local surface plasmon resonance tunability. SERS engineered in this way allowed for the fabrication of a ring-mounted nanostructured substrate where the distribution density of NPs and dielectric constant could be independently fine-tuned. High SERS activity of the substrate was revealed by detecting the enhanced factor of crystal violet and rhodamine 6G molecules, which was up to 1.56 × 10 ⁶ . Moreover, SERS of thiram target molecules confirmed the supersensitivity and repeatability of the substrate as a practical application. The results of this study manifested a low-cost but high-efficiency ring-mounted nanostructured SERS substrate that might be suitable in many fields, including biosensing, medical research, environmental monitoring, and optoelectronics.

Excitation of surface plasmon resonance of metal nanostructures is a promising way to break the limit of optical diffraction and to achieve a great enhancement of the local electromagnetic field by the confinement of optical field at the nanoscale. Meanwhile, the relaxation of collective oscillation of electrons will promote the generation of hot carrier and localized thermal effects. The enhanced electromagnetic field, hot carriers and localized thermal effects play an important role in spectral enhancement, biomedicine and catalysis of chemical reactions. In this review, we focus on surface-plasmon-assisted nanomaterial reshaping, growth and transformation. Firstly, the mechanisms of surface-plasmon-modulated chemical reactions are discussed. This is followed by a discussion of recent advances on plasmon-assisted self-reshaping, growth and etching of plasmonic nanostructures. Then, we discuss plasmon-assisted growth/deposition of non-plasmonic nanostructures and transformation of luminescent nanocrystal. Finally, we present our views on the current status and perspectives on the future of the field. We believe that this review will promote the development of surface plasmon in the regulation of nanomaterials.