To understand the effects of water immersion on the spontaneous combustion of low-rank bituminous coal, and the underlying mechanism, the pore size distributions and active functional groups of water-immersed coal samples were studied. Characterization data were acquired by liquid nitrogen adsorption and Fourier transform infrared spectroscopy. The spontaneous combustion behaviors of the experimental coal samples were assessed based on oxidation kinetics obtained using a programmable temperature device. Water immersion promotes pore development and enhances the activity of functional groups, which in turn stimulates spontaneous combustion. A lower metamorphic degree of coal yields a more obvious effect. Water immersion causes existing pores to expand or forms new pores, such that the specific surface area and total pore volume of the coal increase. Pores with a radius value near 20 nm grew to the greatest extent. The activities of hydroxyl, ether and carbonyl functional groups and of multi-substituted aromatic hydrocarbons in the coal molecules increase, whereas the activities of methyl and methylene groups decrease. The expanded pores provide more space for the coal–oxygen reaction and enhance the functional group activities. These changes increase the risk for spontaneous combustion by increasing the oxygen consumption rate, decreasing the associated activation energy and increasing the pre-exponential factor.

The determination of natural gas content in coal seams is essential to safe mining activities and to estimate gas resources. It is used to estimate methane emissions into workings, which is very important when using preventive measures of methane ignition and explosion. Methane content in a coal seam is mostly determined using a direct method. However, a problem with estimation of gas loss during collecting a sample in a mine occurs in each method. That gas loss is estimated using different procedures. In the Polish mining industry, methane content in a coal seam is mostly determined during roadway advancing faces in coal seams. The differences in procedures for determining methane content in coal in various laboratories gave rise to starting research into developing a new method. This article presents results of study of gas loss unification for the determination of methane content in coal seams. The research focused mainly on determining a uniform method for estimating gas loss using the early adsorption diffusion process. The method of coal sample saturation with methane was used to measure gas desorption rate. Saturation pressures of samples were determined for coal seams in the Upper-Silesian Coal Basin. The analysis of desorption results allowed to determine the dependence between methane content in a coal sample and the initial methane content in a coal seam. It was concluded that the desorption rate was highest within two minutes. For the procedure of coal sampling, gas loss was determined at 12% of both desorbed and residual gases. The presented research results gave rise to developing a uniform method for determining gas content used in Polish coal mining. The method was accepted as the national standard. Methodology using a new gas loss estimation procedure allows for achieving relatively fast results of the determination of methane content in coal seams, which is very important, especially in gassy mines.

Polish coal mines are characterized by severe geological conditions and the co-occurrence of natural hazards. These hazards are associated with methane and dust emissions during mining processes which can provide methane, dust or methane-dust explosions. Besides, there are such natural hazards as gas and rock outbursts, rock bursts, spontaneous combustion of coal and environmental heat load. The mutual influences of various geological conditions, as well as the natural hazards, intensify the increase of the methane explosion hazard. The occurrence of methane explosions in the Polish mining industry between 2013 and 2108 are analyzed. Fatal accidents are compared with similar events in the global mining industry. The methods of preventing the explosion hazard as well as methane emission control in the Polish coal mining sector are presented. Methane hazard prevention should be adapted to levels and other natural hazards, especially those related to ventilation of underground mine. The methods of preventing methane emissions into mine excavations are often contrary to the means of preventing other ventilation-related hazards in the underground mine, e.g. the prevention of spontaneous combustion of coal in the goaf of longwall panel. Therefore, the design of longwall panels should be preceded by a detailed analysis of the results of both methane emission prediction and forecast of other ventilation-related hazards.