Managed aquifer recharge (MAR) is an effective approach to mitigate groundwater decline and spring depletion in karst systems impacted by excessive exploitation. However, the hydrogeological complexity of karst aquifers makes groundwater quantity and quality highly sensitive to human activities, posing challenges for MAR implementation. This study develops an integrated multi-method framework – combining isotopic analysis, flow monitoring, tracer tests, and numerical modeling – to evaluate the effects of MAR and groundwater extraction on karst aquifer dynamics, with a case study in the Baotu Spring system (Jinan, China). To enhance the accuracy of recharge rate quantification, an enhanced isotope mixing model that reduces uncertainties in estimating groundwater recharge ratios from multiple sources was developed, and the MAR rate settings were refined by establishing a quantitative relationship between effective MAR rates and water release rates through river flow monitoring. To improve the solute transport simulations' reliability, we conducted field tracer tests to constrain the effective porosity of the karst aquifer – a parameter typically poorly constrained in such systems. Furthermore, we validated the applicability of the equivalent porous media (EPM) model through rigorous hydrodynamic analysis, using field-measured fracture apertures to calculate Reynolds numbers and verify laminar flow conditions. The results demonstrate that surface water contributes > 80 % of recharge near MAR implementation zones, with MAR efficiency decreasing beyond critical river discharge thresholds. The karst aquifer exhibits laminar flow (effective porosity = 1.08 × 10⁻⁴), confirming the validity of the EPM approach. Modeling reveals that MAR significantly raises water tables, though efficiency varies by different MAR sources, and MAR-induced sulfate concentrations must be maintained below 56.5, 197.8, and 339.1 mg L⁻¹ to meet China's Class I, II, and III groundwater standards, respectively. These findings provide practical guidelines for MAR implementation in temperate semi-arid fissured karst systems.

Metasilicate-rich groundwater could meet the high demand of the international community for high-quality water. In order to comprehensively analyze the genetic mechanism of metasilicate-rich groundwater, and help human communities effectively exploit and utilize high-quality water resources, taking the Ji’nan rock mass area as an example, this study carried out systematic research on the spatial distribution and genetic mechanism of the metasilicate-rich groundwater Based on the regional hydrogeological conditions, the influencing factors on the spatial distribution characteristics of the metasilicate-rich groundwater in the study area were systematically sorted out by means of petrogeochemistry, hydrochemistry, and chemical weathering index analysis, and the accumulation mechanism of the metasilicate-rich groundwater was discussed from the perspective of water-rock interaction. The results show that: (1) On the northwest side and part of the northeast side of Ji’nan rock mass, the metasilicate content of the groundwater samples exceeded 25 mg/L; the metasilicate content on the south, west, and east sides were relatively low; (2) Ji’nan rock mass is mainly composed of gabbro easily weathered, with high SiO₂ content and high weathering degree showing obvious characteristics of desilication. FeS₂ developing along the contact zones between the rock mass and surrounding rocks was easily oxidized to form H₂SO₄, which enhanced the solubility of silicate minerals in the groundwater. Ji’nan rock mass was located in the low-lying position of the monocline structure, which presented better water conservation and recharges conditions. The above factors resulted in the metasilicate-rich groundwater accumulating in the area of Ji’nan rock mass and showed different spatial distribution characteristics.

Karst groundwater is a crucial water source, but it has faced significant environmental risks in recent years. The complexity of the groundwater system necessitates innovative approaches to studying karst groundwater. This paper focuses on the karst groundwater of the Baotu Spring area in Jinan. Using the nanoparticle tracking analysis instrument, it is observed that the collected groundwater contains many natural nanoparticles, with particle sizes mainly ranging from 76.3 to 621.8 nm and concentrations primarily between 0.31 and 5.0 × 10⁵ Particles/L. The transmission electron microscope (TEM) is used to study the characteristics of naturally occurring nanoparticles in the karst groundwater. The results show that the karst groundwater mainly contains particles of Ca, Na, Fe, Al, Si, and other elements, which exist in granular and irregular forms. The size of individual particles varies from 40 to 600 nm, and they are mostly amorphous and monocrystalline. The characteristics of the particles suggest that the direct recharge area mainly receives infiltration from atmospheric precipitation, with minimal influence from human activities and agriculture. In contrast, the indirect recharge and discharge areas are more significantly affected by external environments, including domestic sewage, industrial wastewater discharge, and agricultural fertilizers. These findings also suggest that elements can be transported in particle form during water-rock interactions, potentially playing a significant role in the cycling of elements between water and rocks. The particles in the study area are situated in a relatively oxidized environment, suggesting that fracture and oxidation are the main processes for particle formation. Particles can effectively transport metallic elements in groundwater, offering fresh perspectives on the migration of these elements and acting as carriers for inorganic substances, thereby increasing their mobility in aquatic environments. Given the widespread presence of natural nanoparticles in the water cycle system, some stable nanoparticles can serve as new types of groundwater tracing agents during the groundwater migration process.

Reduction in river discharge and sediment load has left deltaic lobes in the world’s many river deltas starving, but knowledge of how the subaqueous topography of these abandoned subdeltas responds to environmental changes is limited. In this study, we aimed to determine the long-term dynamics of the subaqueous seabed of abandoned delta lobes to advance current knowledge. As a case study, we selected an abandoned subdelta on the Yellow River Delta of the Bohai Sea, China, for which three-decade long (1984–2017) bathymetric data and long-term river discharge and sediment load records are available. We analyzed the seafloor surface change and quantified the void space from the sea water surface to the seafloor. In addition, we surveyed the seafloor surface with an M80 unmanned surface vehicle carrying a multibeam echo sounder system (MBES) in 2019 to obtain high-resolution microtopography information. We found that a net volume of 5.3 × 10⁸ m³ of sediment was eroded from the study seabed within an area of 3.6 × 10⁸ m² during 1984–2017. This volumetric quantity is equivalent to 6.89 billion metric tons of sediment, assuming a bulk density of 1.3 t/m³ for the seabed sediment. The seabed erosion from 0 to −5 m, from −5 to −10 m, and below −10 m has showed a similar increasing trend over the past 33 years. These findings suggest that seabed erosion in this abandoned subdelta will very likely continue, and that other abandoned delta lobes in the world may have been experiencing similar seabed erosion due to the interruption of the sediment supply and sea level rise. It is not clear if the seabed erosion of abandoned delta lobes would have any effect on the stability of the coastal shoreline and continental shelf.