Thermal transport properties for the isotropic and anisotropic characterization of nanolayers have been a significant gap in the research over the last decade. Multiple studies have been close to determining the thermal conductivity, diffusivity, and boundary resistance between the layers. The methods detailed in this work involve non-contact frequency domain pump-probe thermoreflectance (FDTR) and photothermal radiometry (PTR) methods for the ultraprecise determination of in-plane and cross-plane thermal transport properties. The motivation of one of the works is the advantage of the use of amplitude (TR signal) as one of the input parameters along with the phase for the determination of thermal parameters. In this article, we present a unique strategy for measuring the thermal transport parameters of thin films, including cross-plane thermal diffusivity, in-plane thermal conductivity, and thermal boundary resistance as a comprehensively reviewed article. The results obtained for organic and inorganic thin films are presented. Precise ranges for the thermal conductivity can be across confidence intervals for material measurements between 0.5 and 60 W/m-K for multiple nanolayers. The presented strategy is based on frequency-resolved methods, which, in contrast to time-resolved methods, make it possible to measure volumetric-specific heat. It is worth adding that the presented strategy allows for accurate (the signal in both methods depends on cross-plane thermal conductivity and thermal boundary resistance) and precise measurement.

Measurement of thermal properties of thin films is challenging. In particular, thermal characterization is very difficult in semi-transparent samples. Here, we use two photothermal methods to obtain information about the thermal diffusivity as well as thermal conductivity of azoheteroarene functionalized polymer thin layers. The photothermal beam deflection (PBD) method is employed to gather data directly on thermal conductivity and thermal diffusivity, while the thermal lens (TL) method is employed to measure the effective thermal diffusivity. Consequently, the thermal diffusivity of the layers is indirectly estimated from the effective thermal diffusivity using a well-established theoretical relationship. Despite the utilization of distinct methods, our study reveals a remarkable consistency in the highly accurate results obtained from both approaches. This remarkable agreement reaffirms the reliability and mutual compatibility of the employed methods, highlighting their shared ability to provide accurate and congruent outcomes.

The transfer matrix approach is used to study the optical characteristics of thermal radiation in a one-dimensional photonic crystal (1DPC) with metamaterial. In this method, every layer within the multilayer structure is associated with its specific transfer matrix. Subsequently, it links the incident beam to the next layer from the previous layer. The proposed structure is composed of three types of materials, namely InSb, ZrO₂, and Teflon, and one type of epsilon-negative (ENG) metamaterial and is organized in accordance with the laws of sequencing. The semiconductor InSb has the capability to adjust bandgaps by utilizing its thermally responsive permittivity, allowing for tunability with temperature changes, while the metamaterial modifies the bandgaps according to its negative permittivity. Using quasi-periodic shows that, in contrast to employing absolute periodic arrangements, it produces more diverse results in modifying the structure’s band-gaps. Using a new sequence arrangement mixed-quasi-periodic (MQP) structure, which is a combination of two quasi periodic structures, provides more freedom of action for modifying the properties of the medium than periodic arrangements do. The ability to control thermal radiation is crucial in a range of optical applications since it is frequently unpolarized and incoherent in both space and time. These configurations allow for the suppression and emission of thermal radiation in a certain frequency range due to their fundamental nature as photonic band-gaps (PBGs). So, we are able to control the thermal radiation by changing the structure arrangement. Here, the We use an indirect method based on the second Kirchoff law for thermal radiation to investigate the emittance of black bodies based on a well-known transfer matrix technique. We can measure the transmission and reflection coefficients with associated transmittance and reflectance, T and R, respectively. Here, the effects of several parameters, including the input beam’s angle, polarization, and period on tailoring the thermal radiation spectrum of the proposed structure, are studied. The results show that in some frequency bands, thermal radiation exceeded the black body limit. There were also good results in terms of complete stop bands for both TE and TM polarization at different incident angles and frequencies. This study produces encouraging results for the creation of Terahertz (THz) filters and selective thermal emitters. The tunability of our media is a crucial factor that influences the efficiency and function of our desired photonic outcome. Therefore, exploiting MQP sequences or arrangements is a promising strategy, as it allows us to rearrange our media more flexibly than quasi-periodic sequences and thus achieve our optimal result.

We demonstrate that dopant inhomogeneity strongly suppresses thermal conductivity in Cd/Eu co-doped, non-polar a-plane-oriented ZnO films grown on r-plane sapphire (Al₂O₃) by plasma-assisted molecular beam epitaxy. X-ray diffraction confirms the a-plane-oriented ZnO without detectable secondary phases. Cross-sectional scanning electron microscopy shows continuous films with well-defined interfaces, and secondary-ion mass spectrometry depth profiling identifies Cd/Eu incorporation through the film thickness and a sharp Zn/O drop at the substrate interface. Cross-plane thermal transport was measured at room temperature using frequency-domain photothermal infrared radiometry (PTR) and analyzed by fitting the complex PTR amplitude and phase with a multilayer heat-diffusion model. The extracted thermal conductivity ($\kappa$) spans ~3.7–6.3 W·m⁻¹·K⁻¹. The lowest $\kappa$ values correlate with increased Eu-distribution inhomogeneity, consistent with enhanced phonon scattering and reduced effective cross-plane heat transport.

In this study we investigate the electrical properties in the transparent conductive polymer poly(3,4-ethylendioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) and Cu-doped polymer (PEDOT:PSS 1.3% + CuCl₂) using Hall measurements under the Van der Pauw configuration. The influence of doping on the electrical conductivity, Hall mobility, and carrier concentration is demonstrated in Cu-PEDOT:PSS and compared with pure PEDOT:PSS. Through this, we figured out there are difficulties in preparing Cu-doped (PEDOT:PSS 1.3% + CuCl₂) polymeric thin films. The sheet resistance was measured to determine the electrical conductivity, aided by knowledge of the thin film thickness. Temperature dependency was evaluated using a closed cycle cryostat, covering temperatures ranging from 8K to 300 K. These comprehensive measurements provide valuable insights into the electrical behavior and temperature characteristics of PEDOT:PSS and PEDOT:PSS 1.3% + CuCl₂, facilitating the development of high-performance organic electronic devices.

We demonstrate that dopant inhomogeneity strongly suppresses thermal conductivity in Cd/Eu co-doped, non-polar a-oriented ZnO films grown on r-plane sapphire (Al₂O₃) by plasma-assisted molecular beam epitaxy. Structural characterization by θ-2θ XRD confirms a-oriented ZnO without detectable secondary phases. Cross-sectional SEM shows continuous films with well-defined interfaces, and SIMS depth profiling verifies Cd/Eu incorporation through the film thickness and a sharp Zn/O drop at the substrate interface. Optical transmittance and Tauc analysis reveal composition-dependent shifts of the absorption edge and band gap. Cross-plane thermal transport was measured at room temperature using frequency-domain photothermal infrared radiometry (PTR) and analyzed by fitting the complex PTR amplitude and phase with a multilayer heat-diffusion model. The extracted thermal conductivity spans ~3.7 - 6.3 Wm-1K-1. The lowest k values correlate with increased defect non-uniformity, consistent with enhanced phonon scattering and reduced effective cross-plane heat transport.