Gas sensors play an important role in many areas of human life, including the monitoring of production processes, occupational safety, food quality assessment, and air pollution monitoring. Therefore, the need for gas sensors to monitor hazardous gases, such as ammonia, at low operating temperatures has become increasingly important in many fields. Sensitivity, selectivity, low cost, and ease of production are crucial characteristics for creating a capillary network of sensors for the protection of the environment and human health. However, developing gas sensors that are not only efficient but also small and inexpensive and therefore integrable into everyday life is a difficult challenge. In this paper, we report on a resistive sensor for ammonia detection based on thin V2O5 nanosheets operating at room temperature. The small thickness and porosity of the V2O5 nanosheets give the sensors good performance for sensing ammonia at room temperature (RT), with a relative change of resistance of 9.4% to 5 ppm ammonia (NH3) and an estimated detection limit of 0.4 ppm. The sensor is selective with respect to the seven interferents tested; it is repeatable and stable over the long term (four months). Although V2O5 is generally an n-type semiconductor, in this case the nanosheets show a p-type semiconductor behavior, and thus a possible sensing mechanism is proposed. The device’s performance, along with its size, low cost, and low power consumption, makes it a good candidate for monitoring freshness and spoilage along the food supply chain.
23 October 2017 in Journal of Electronic Materials
Three different ZnO nanostructures, dense nanorods, dense nanowires, and sparse nanowires, were synthesized between Pt electrodes by on-chip hydrothermal growth at 90°C and below. The three nanostructures were characterized by scanning electron microscopy and x-ray diffraction to identify their morphologies and crystal structures. The three ZnO nanostructures were confirmed to have the same crystal type, but their dimensions and densities differed. The NO2 gas-sensing performance of the three ZnO nanostructures was investigated at different operation temperatures. ZnO nanorods had the lowest response to NO2 along with the longest response/recovery time, whereas sparse ZnO nanowires had the highest response to NO2 and the shortest response/recovery time. Sparse ZnO nanowires also performed best at 300°C and still work well and fast at 200°C. The current–voltage curves of the three ZnO nanostructures were obtained at various temperatures, and the results clearly showed that sparse ZnO nanowires did not have the linear characteristics of the others. Analysis of this phenomenon in connection with the highly sensitive behavior of sparse ZnO nanowires is also presented.
A 2-D thermal velocity microsensor for use as a navigational aid and for flow measurements on a miniaturized submersible is developed in this paper. The sensor with nickel heater and temperature sensors on a Pyrex substrate, designed for mounting on the outside of the submersible hull, is fabricated and tested in an application-like environment and proven to be able to measure water speed from zero to 40 mm/s with a power consumption less than 15 mW and determine the flow direction with an error less than ±8°. Finite Element Analysis is used to investigate design and operation parameters and possible biofouling effects on the sensor signal. The effect on shape and orientation of the sensor's mounting surface is also studied.
1 November 2006 in Journal of Spacecraft and Rockets
In this work, a gas valve using a microstructured silicon valve lid and a stainless steel valve seat clamped axially together in an aluminum cylinder is investigated. The difference in coefficient of thermal expansion of these components makes the valve open and close on a temperature change. A simple model accounting for elastic deformation of the system’s components is proposed to facilitate design of the valve. By means of a helium leak detector, a typical increase in flow rate from 1.0×10−8to1.0×10−4sccs gaseous helium under a pressure of up to 10bars was observed upon the increase of temperature from 12 to around 98°C, after a single breaking-in. Plastic deformation of the valve seat as a consequence of an imprint of the microstructured valve lid and contaminating particles was studied. Microscopy confirmed a tolerance for particles of up to a few micrometers in diameter. Larger particles were found to be a possible cause of failure.