Perovskite materials hold great potential as photovoltaic power sources for portable devices owing to their mechanical flexibility and high performance; however, the flexibility and efficiency require further improvement to attain practical viability. We investigated the mechanical fracture behavior of polycrystalline perovskite films by varying the substrate thickness and applying the neutral plane concept. This enabled us to fabricate a crack-free perovskite film on an ultra-thin substrate (∼2.5 μm) and to demonstrate ultra-flexible solar cells with high efficiency (17.03%) with unprecedented flexibility sustained after 10 000 cycles of bending at a 0.5 mm radius. This represents a high efficiency of 13.6% for large-area flexible perovskite solar cells (1.2 cm2), fabricated by using a hybrid transparent electrode composed of a metal mesh grid and conducting polymer. Using a protective layer to achieve the neutral plane concept, our ultra-flexible perovskite solar cells are demonstrated to be durable even after 100 crumpling cycles. Our approach paves the way to fabricate flexible perovskite solar cells for portable power sources.
Hydrogels have diverse chemical properties and can exhibit reversibly large mechanical deformations in response to external stimuli; these characteristics suggest that hydrogels are promising materials for soft robots. However, reported actuators based on hydrogels generally suffer from slow response speed and/or poor controllability due to intrinsic material limitations and electrode fabrication technologies. Here, we report a hydrogel actuator that operates at low voltages ( 50%, energy density > 7 × 10 5 joules per cubic meter, and power density > 3 × 10 4 watts per cubic meter), surpassing existing hydrogel actuators and other types of electroactive soft actuators. The enhanced performance of our actuator is due to the formation of wrinkled nanomembrane electrodes that exhibit high conductivity and excellent mechanical deformation through capillary-assisted assembly of metal nanoparticles and deswelling-induced wrinkled structures. By applying an electric potential through the wrinkled nanomembrane electrodes that sandwich the hydrogel, we were able to trigger a reversible and substantial electroosmotic water flow inside a hydrogel film, which drove the controlled swelling of the hydrogel. The high energy efficiency and power density of our wrinkled nanomembrane electrode–induced actuator enabled the fabrication of an untethered insect-scale aquabot integrated with an on-board control unit demonstrating maneuverability with fast locomotion speed (1.02 body length per second), which occupies only 2% of the total mass of the robot.
We present a mechanical crack-based strain sensor with metal films by introducing an inter-layer. Two inter-layers are used; Cr layer is for generating cracks and MoO3layer for enhancing the adhesion between the substrate and the metal layer.