Understanding the history of the Greenland Ice Sheet (GrIS) is critical for determining its sensitivity to warming and contribution to sea level; however, that history is poorly known before the last interglacial. Most knowledge comes from interpretation of marine sediment, an indirect record of past ice-sheet extent and behavior. Subglacial sediment and rock, retrieved at the base of ice cores, provide terrestrial evidence for GrIS behavior during the Pleistocene. Here, we use multiple methods to determine GrIS history from subglacial sediment at the base of the Camp Century ice core collected in 1966. This material contains a stratigraphic record of glaciation and vegetation in northwestern Greenland spanning the Pleistocene. Enriched stable isotopes of pore-ice suggest precipitation at lower elevations implying ice-sheet absence. Plant macrofossils and biomarkers in the sediment indicate that paleo-ecosystems from previous interglacial periods are preserved beneath the GrIS. Cosmogenic ²⁶Al/¹⁰Be and luminescence data bracket the burial of the lower-most sediment between 0.7 to 1.4 Ma. In the upper-most sediment, cosmogenic ²⁶Al/¹⁰Be data require exposure within the last 1.0 ± 0.1 My. The unique subglacial sedimentary record from Camp Century documents at least two episodes of ice-free, vegetated conditions, each followed by glaciation. The lower sediment derives from an Early Pleistocene GrIS advance. ²⁶Al/¹⁰Be ratios in the upper-most sediment match those in subglacial bedrock from central Greenland, suggesting similar ice-cover histories across the GrIS. We conclude that the GrIS persisted through much of the Pleistocene but melted and reformed at least once since 1.1 Ma. Significance Understanding Greenland Ice Sheet history is critical for predicting its response to future climate warming and contribution to sea-level rise. We analyzed sediment at the bottom of the Camp Century ice core, collected 120 km from the coast in northwestern Greenland. The sediment, frozen under nearly 1.4 km of ice, contains well-preserved fossil plants and biomolecules sourced from at least two ice-free warm periods in the past few million years. Enriched stable isotopes in pore ice indicate precipitation at lower elevations than present, implying ice-sheet absence. The similarity of cosmogenic isotope ratios in the upper-most sediment to those measured in bedrock near the center of Greenland suggests that the ice sheet melted and re-formed at least once during the past million years.

Past interglacial climates with smaller ice sheets offer analogs for ice sheet response to future warming and contributions to sea level rise; however, well-dated geologic records from formerly ice-free areas are rare. Here we report that subglacial sediment from the Camp Century ice core preserves direct evidence that northwestern Greenland was ice free during the Marine Isotope Stage (MIS) 11 interglacial. Luminescence dating shows that sediment just beneath the ice sheet was deposited by flowing water in an ice-free environment 416 ± 38 thousand years ago. Provenance analyses and cosmogenic nuclide data and calculations suggest the sediment was reworked from local materials and exposed at the surface <16 thousand years before deposition. Ice sheet modeling indicates that ice-free conditions at Camp Century require at least 1.4 meters of sea level equivalent contribution from the Greenland Ice Sheet.

The need for accurate quantification of lead concentrations in urban centers around the world is turning attention towards rapid methods for contamination assessment. Portable X‐ray Fluorescence (pXRF) has been recognized as a more accessible alternative to traditional digestion methods. This study was conducted to produce measurement corrections for in‐situ pXRF measurements conducted on field soils under varying conditions of moisture, organic matter (OM) content, and particle size heterogeneity. Urban forest soils were analyzed for Pb under increasing soil moisture, OM, and coarse fraction contents with two different pXRF and the results were compared to reverse aqua regia digestions. While both instruments showed a strong correlation despite using different calibration methods, correction of pXRF data to digestion values improved accuracy but potentially underestimated Pb concentrations. We propose an empirical correction equation derived from the regression of variance between theoretical and observed concentrations to correct for moisture effects. OM and particle size heterogeneity did not produce a significant effect on Pb measurement and did not warrant correction. Our study confirms other work showing that pXRF provides an accurate and precise alternative to traditional digestion methods for Pb screening, provided that moisture is corrected.