One of the most significant elements in the environment is arsenic (As). It is a hazardous metalloid that causes contamination of soil and water supplies as a result of numerous anthropogenic and natural sources. This pollution has detrimental impacts on human health and the ecosystem, making it crucial to monitor and control. The release of As from minerals into the soil and groundwater depends on the kind of mineral, pH, and redox conditions. As is typically found in two forms, trivalent arsenic (As3+, arsenite) and pentavalent arsenic (As5+, arsenate), both of which are inorganic and extremely deadly. When it comes to toxicity, arsenite is more dangerous than arsenate. Many people have been affected by As poisoning, due to exposure to As through water and food. Nowadays, accurate, fast measurement of As in the field remains a technical challenge; however, the X-ray fluorescence method is considered the most reliable, cost effective and capable of measuring a wide spectrum of metals. Health risk assessment is a crucial parameter to estimate the health hazards of the As molecule. The risk assessment approach proposed by the USEPA is common and widely used, amongst others. On the numerous health risk assessment models/frameworks used to foresee the carcinogenic and non-carcinogenic health impacts brought on by As-contaminated water, little information is currently accessible. This discussion also emphasizes the need for more study on the risks to human health posed by specific As species (both organic and inorganic) found in As-contaminated water.
On the Curonian Spit, the leading conservation issue is an opposition between the two contrasting nature-management principles—anthropocentricity and biocentricity. Land managers still waver between the two options, and the worst-case scenario materializes as a rapid proliferation of vegetation to the accumulative sandplain (palve). It results in the decline of sand drift to the mobile dunes. This article aims to examine how climate change affects the coastal dune landscape and to identify current dune protection and management priorities. The analysis of hydroclimatic changes; succession patterns in forest, herbaceous, and open-sand ecosystems; and phenological-based evaluation (NDVI from MODIS, 2000–2020), influencing possible management directions, were carried out in this study. The results show the significant hydro-climatic changes (air temperature, precipitation, and sea level) occurring over the last thirty years. They influence the prevailing overgrowth trends in recent decades, especially in herbaceous ecosystems. Therefore, if the EU’s priority habitat—open-sand ecosystems—is to be preserved, the main policy recommendation is to apply adequate management tools such as grazing, and to pay more attention to the aesthetic ecosystem services of the mobile dunes parallel to biodiversity conservation.
Geochemical and lithological parameters of sapropel in lakes, combined with pollen data and radiocarbon 14C dating, contain a wide spectrum of environmental information. This includes records of fluctuations of water level and changes of conditions of sedimentation, accumulation of organic matter and chemical elements due to climate change, human impacts and other environmental changes. Rising concentrations of hazardous substances in the natural sediments are likely to be a high risk to the natural environment. At the same time, they can greatly reduce opportunities for environmental engineering of lakes. Four lakes with different trophic states and anthropogenic pressures were chosen for this study in Lithuania. Higher concentrations of elements like Cr, Cu and Zn were not only detected in the top most layers of sapropel but also in deeper layers and are attributed to lithogenic association of trace elements in such deep layers. Concentrations of Pb were detected only in upper layers of sapropel which indicates the impact of anthropogenic activity. The main source of heavy metals was multidimensional anthropogenic pollution leading to a biogenic–anthropogenic association of elements. Sapropel with low concentrations of heavy metals exhibits a different inter-association matrix because most of the elements tend to form lithogenic–clastogenic associations.