The occurrence of pesticides in soil has become a highly significant environmental problem, which has been increased by the vast use of pesticides worldwide and the absence of remediation technologies that have been tested at full-scale. The aim of this review is to give an overview on technologies really studied and/or developed during the last years for remediation of soils contaminated by pesticides. Depending on the nature of the decontamination process, these techniques have been included into three categories: containment-immobilization, separation or destruction. The review includes some considerations about the status of emerging technologies as well as their advantages, limitations, and pesticides treated. In most cases, emerging technologies, such as those based on oxidation-reduction or bioremediation, may be incorporated into existing technologies to improve their performance or overcome limitations. Research and development actions are still needed for emerging technologies to bring them for full-scale implementation.

The purpose of this study was to determine the degree of contamination with polycyclic aromatic hydrocarbons (PAHs) in samples of urban soil from three European cities: Glasgow (UK), Torino (Italy) and Ljubljana (Slovenia). Fifteen PAHs (naphthalene, acenaphthene, fluorene, phenanthrene, anthracene, fluoranthene, pyrene, benzo[a]anthracene, chrysene, benzo[b]fluoranthene, benzo[k]fluoranthene, benzo[a]pyrene, dibenzo[a,h]anthracene, benzo[g,h,i]perylene, indeno[1,2,3-c,d]pyrene) were measured in urban soil samples, using harmonised sampling, sample extraction and analyte quantification methods. Although the mean concentration of each PAH in urban soils of each city showed a wide range of values, high levels of contamination were only evident in Glasgow, where the sum of concentrations of 15 PAHs was in the range 1487–51 822 μg kg⁻¹, cf. ranges in the other two cities were about ten-fold lower (89.5–4488 μg kg⁻¹). The three predominant PAHs were phenanthrene, fluoranthene and pyrene, with the sum of these compounds about 40% of the total PAH content. These data, together with some special molecular indices based on ratios of selected PAHs, suggest pyrogenic origins, especially motor vehicle exhausts, to be the major sources of PAHs in urban soils of the three cities. The largest concentrations for PAHs were often found in sites close to the historic quarters of the cities. Overall, the different climatic conditions, the organic carbon contents of soil, and the source apportionment were the dominant factors affecting accumulation of PAHs in soil.

Glyphosate (GPS) is an herbicide currently used on olive crops in Spain, and can be transported to the nearby reservoirs currently used for human consumption. The purpose of this work was to study the behaviour and environmental fate of GPS in water and sediments of the Vibora Reservoir, its tributary river, and the surrounding agricultural soils to assess the risk of water pollution of this reservoir. The adsorption of GPS by different matrices was as follows: heading of the reservoir sediment (Cabecera)>tail sediment (Cola)>soils>Vibora sediment. The highest amount of oxides (especially Fe oxides) was observed in sediments from Cabecera and Cola whereas the lowest values were recorded on Vibora sediment. Results indicate that the highest GPS adsorption is due to the amorphous oxides and the edge sites of the clay minerals. Glyphosate adsorption increased with decreasing pH from 8 to 7. The desorption percentage of GPS from the four soils studied ranged only from 0.40 to 1.22%. Desorption was almost irreversible for Cabecera and Cola sediments, with values between 0 and 1.1%. Conversely, Vibora sediment presented about 20% desorption, probably due to its coarse texture and lower levels of amorphous oxides. Hockey-stick first-order kinetics was the best descriptor for water glyphosate dissipation at the Cabecera and Cola locations, and simple first-order kinetic for the water from the tributary Vibora River. The half-lives (DT50) were between 6.3 and 11.0days. The rapid degradation of GPS in surface waters and its practically irreversible sorption on these soils and sediments implies that GPS use in similar agricultural areas is of very low environmental risk. This manuscript also outlines the importance of the presence of photo-sensitizers in waters in the degradation routes of GPS in reservoirs.