The object of this study was to evaluate the effect of sewage sludge biochar on adsorption and mobility of Cr, Mn, Cu, and Zn. Biochar (BC400) was produced via pyrolysis of municipal sewage sludge at 400 °C. Maximum adsorption capacities (q_m) for Zn, Cr, Mn, and Cu were 5.905, 5.724, 5.681, and 5.342 mg·g⁻¹, respectively, in the mono-metal solution and 2.475, 8.204, 1.01, and 5.415 mg·g⁻¹, respectively, in the multi-metal solution. The adsorption capacities for Mn, Cu, and Zn decreased in the multi-metal solution due to competitive adsorption, whereas the capacity for Cr increased. Surface precipitation is an important mechanism in the sorption of these metals on BC400. The 360-day incubation experiment showed that BC400 application reduced metal mobility in contaminated soils, which was attributed to the substantial decreases in the acid-soluble fractions of Cr, Mn, Cu, and Zn (72.20%, 70.38%, 50.43%, and 29.78%, respectively). Furthermore, the leaching experiment using simulated acid rain indicated that the addition of BC400 enhanced the acid buffer capacity of contaminated soil, and the concentration of Cr, Mn, Cu, and Zn in the leachate was lower than in untreated soil. Overall, this study indicates that sewage sludge biochar application reduces the mobility of heavy metal in co-contaminated soil, and this adsorption experiment is suitable for the evaluation of biochar properties for remediation.

At present, there are significant knowledge gaps in the research on the resource and environmental effects of rare earth exploitation, especially the carbon emission coefficient. This study applies the life cycle assessment approach to calculate the carbon footprint of producing mixed oxide rare earths using ionic rare earth resources and analyze the sources and influencing factors of the carbon footprint. The results show that the carbon footprint of producing 1 kg of mixed oxide rare earths using ionic rare earths is 17.8~24.3 kg CO₂ eq, but its uncertainty is 15.54%; the total carbon footprint from 2012 to 2017 reaches 1.6 × 10⁸~2.19 × 10⁸ kg CO₂ eq/year, and after 2018, the carbon footprint decreases to 1.51 × 10⁸~2.07 × 10⁸ kg CO₂ eq /year. The total carbon footprint of illegal mining is around 1.50 × 10⁸~1.59 × 10⁸ kg CO₂ eq/ year. In principle, the higher the recovery rate, the lower the carbon footprint of 1 kg REO production, but with the increase in the recovery rate, the carbon footprint reduction benefit brought by the increase in the unit recovery rate shows a downward trend. Finally, the new generation of magnesium salt leaching technology, while alleviating ammonia nitrogen pollution in ionic rare earth mines, will increase the carbon footprint of the product.