In this study, the laboratory scale production of activated carbon synthesized from PVC with CoCl2 and H3PO4, which is cheaper and has a good yield source material, is reported.
20 January 2023 in Materials for Renewable and Sustainable Energy
The primary goal of the current study is to improve the specific capacitance of electric double-layer (EDLC) device using biomass (Tribulus Terrestris) derived activated carbon electrodes synthesized by chemical activation method. Furthermore, high surface area carbon electrodes are characterized using X-ray diffraction (XRD), RAMAN spectroscopy, and scanning electron microscopy (SEM) to confirm the morphological structure. Finally, the electrochemical performance of fabricated EDLC proves a good agreement data using Cyclic Voltammetry (CV), Low Impedance Spectroscopy (LIS), and Galvanostatic Charge–Discharge (GCD) analysis showing the high specific capacitance of 115 Fg−1 for the optimized 1:2 activated carbon material.
In this paper, we have used polymer polyethylene oxide as a host matrix and novel electrolyte ionic liquid 1-ethyl-3-methylimidazolium tricyanomethanide as an dopant to increase ionic mobility. Different characterization techniques like Electrochemical impedance spectroscopy, dielectric measurement, Fourier transform, X-ray diffraction, polarized optical microscopy, thermogravinometric analysis were used to identify the electrical, optical, structural and thermal properties. A laboratory scale supercapacitor has been fabricated using optimized solid polymer electrolyte film as an electrolyte and porous carbon derived from corn starch which shows a specific capacitance 13.6 F/g at 50 mV/s scan rate.
In this study, a new biopolymer electrolyte (BPE) is successfully developed using corn starch complexed with ammonium iodide (NH4I) as host, and low viscosity ionic liquid 1-Ethyl, 3-Methyl Imidazolium Thiocyanate (EMImSCN), as a plasticizer. This ionic liquid doped BPE shows high ionic conductivity of the order 10−4 S/cm and electrochemical stability window more than 3 V, which is suitable for electrochemical application. The ionic transference number (tion) of 0.98 confirms the system to be predominantly ionic in nature. Fourier transform infrared spectroscopy (FTIR) shows complex nature, while polarized optical microscopy (POM) gives us an idea about the semi-crystalline nature of BPE. Maximum conducting ionic liquid doped BPE sandwiched electric double layer capacitor (EDLC) and dye sensitize solar cell (DSSC) shows efficient performance.
23 January 2023 in Journal of Electronic Materials
Conducting sodium iodide (NaI) doped polyethylene oxide (PEO) freestanding electrolyte films are prepared by solution cast technique. Electrical, Structural, and device performances are given in detail. Maximum conducting polymer electrolyte has been used to develop electric double-layer capacitors (EDLCs) as well as the dye-sensitized solar cell (DSSC) which shows that ion-conducting polymer electrolyte is a novel candidate for energy devices.