This review exclusively addresses material systems primarily based on poly(vinyl alcohol) (PVA), one of the most popular water-soluble biopolymers, for their use in packaging applications with the primary objective of reducing petrobased plastic waste. In addition, some typical PVA blends and nanocomposites are discussed as comparative studies for material packaging. Structural characteristics, mechanical, thermal, and barrier properties, in addition to biodegradation of these multiple material systems are summarized in a systematic manner. Finally, associated fabrication processing methods together with the most popular theoretical models used for the permeability of PVA nanocomposites are also reviewed in detail. GRAPHICAL ABSTRACT

The cement industry plays a significant role in global carbon emissions, underscoring the urgent need for measures to transition it toward a net-zero carbon footprint. This paper presents a detailed plan to this end, examining the current state of the cement sector, its carbon output, and the imperative for emission reduction. It delves into various low-CO₂ technologies and emerging innovations such as alkali-activated cements, calcium looping, electrification, and bio-inspired materials. Economic and policy factors, including cost assessments and governmental regulations, are considered alongside challenges and potential solutions. Concluding with future prospects, the paper offers recommendations for policymakers, industry players, and researchers, highlighting the roadmap's critical role in achieving a carbon-neutral cement sector.