The high gravimetric energy density and environmental benefits place hydrogen as a promising alternative to the widely used fossil fuels, which is however impeded by the lack of safe, energy-saving and cost-effective H₂ storage systems. The use of solid adsorbents as candidate materials offers a less energy-intensive way of storing hydrogen. The exceptional diversity and tunability of the chemical composition, topological structure, and surface chemistry together with large surface area position porous metal–organic frameworks as promising hydrogen storage material candidates. In this review, we first introduce several classes of important metal–organic frameworks for hydrogen storage, and then highlight the progress associated with the key challenges to be addressed, including the improvement of hydrogen–framework interaction required for enhancing room-temperature hydrogen storage capacities, and the optimization/balance of both gravimetric and volumetric storage/working capacities. In particular, the strategies used to tune and enhance hydrogen binding energies have been comprehensively reviewed. Future development prospects and related challenges of using porous metal–organic frameworks as hydrogen storage materials are also outlined. This feature review provides a wide perspective and insightful thoughts and suggestions for hydrogen storage using metal–organic frameworks, and promotes the further development of hydrogen storage materials to realize a hydrogen economy.

Metal–organic frameworks (MOFs), as an emerging class of porous materials, excel in designability, regulatability, and modifiability in terms of their composition, topology, pore size, and surface chemistry, thus affording a huge potential for addressing environment and energy-related challenges. In particular, MOFs can be applied as porous adsorbents for the purification of industrially important hydrocarbons through certain process-efficient separation schemes based on selectivity-reversed adsorption and multicomponent separation. Moreover, the vast combination possibilities and controllable and engineerable luminescent units of MOFs make them a versatile platform to develop functionally tailored materials for luminescent sensing and optical data encryption. In this feature article, we summarize the recent progress in the use of porous MOFs for the separation and purification of acetylene (C₂H₂) and ethylene (C₂H₄) based on selectivity-reversed adsorption and multicomponent separation strategies. Moreover, we highlight the advances over the past three years in the field of MOF-based luminescent materials for thermometry, turn-on sensing, and information encryption.