The effect of Mg, Si, N, and O ion implantation (with doses in the range in epitaxially grown GaN samples has been studied using Raman spectroscopy. It is found that implantation increases the static disorder and activates modes that were not allowed in the as-grown material. More specifically it causes the appearance of three additional Raman peaks at 300, 420, and 670 cm−1. It is found that the position of these peaks does not depend on the type of the implant and thus they do not correspond to local vibrational modes. They are attributed to disorder activated Raman scattering (300 cm−1) and/or to implantation induced N and Ga vacancies or interstitials (420 and 670 cm−1). Finally, ion implantation causes a marginal increase of the build-in hydrostatic stress.
MnFe 2 O 4 nanoparticles of low inversion degree present optimized magnetization with high ( T 2 ) relaxation (345.5 s −1 mM −1 ) and heating efficiency (286 W g −1 ).
4 July 2014 in The Journal of Physical Chemistry C
Hexagonal, cubic, and mixed phase GaN samples grown by molecular beam epitaxy are studied using near-edge x-ray absorption fine structure (NEXAFS) spectroscopy. The spectra were recorded at the N-K-edge, at several angles of incidence. It is shown that the N-K-edge NEXAFS spectra, which are proportional to the -partial density of states in the conduction band, are characteristic of the cubic or hexagonal structure of the examined crystal. The spectra of the cubic sample do not depend on the angle of incidence (θ), contrary to the spectra of the hexagonal sample in which the areas under the NEXAFS resonances depend linearly on From the fitting of the lines where are the areas under the resonances and and are constants, the directions of maximum electron charge density with respect to the normal to the surface are determined for the hexagonal sample. The energy positions of the absorption edge and the NEXAFS resonances in the spectra from the cubic sample are different from those of the hexagonal sample and in either case are independent of θ. Contrary to that, the energy positions of the NEXAFS resonances in a mixed phase sample have a characteristic angular dependence and shift between the energies corresponding to the cubic and hexagonal polytypes. Based on this observation, we propose that the spectrum of the mixed-phase sample can be approximated as the weighted average of the spectra from the pure cubic and hexagonal samples. From this approximation the coexisting fractions of α- and β-GaN in a mixed-phase sample are determined and they are found in good agreement with results from high resolution transmission electron microscopy and x-ray diffraction.