This work investigated the influence of process parameters on the densification, microstructure, and mechanical properties of a Ti–6Al–4V alloy printed by selective laser melting (SLM), followed by annealing heat treatment. In particular, the evolution mechanisms of the microstructure and mechanical properties of the printed alloy with respect to the annealing temperature near the β phase transition temperature were investigated. The process parameter optimization of SLM can lead to the densification of the printed Ti–6Al–4V alloy with a relative density of 99.51%, accompanied by an ultimate tensile strength of 1204 MPa and elongation of 7.8%. The results show that the microstructure can be tailored by altering the scanning speed and annealing temperature. The SLM-printed Ti–6Al–4V alloy contains epitaxial growth β columnar grains and internal acicular martensitic α′ grains, and the width of the β columnar grain decreases with an increase in the scanning speed. Comparatively, the printed alloy after annealing in the range of 750–1050 °C obtains the microstructure consisting of α + β dual phases. In particular, network and Widmanstätten structures are formed at the annealing temperatures of 850 °C and 1050 °C, respectively. The maximum elongation of 14% can be achieved at the annealing temperature of 950 °C, which was 79% higher than that of as-printed samples. Meanwhile, an ultimate tensile strength larger than 1000 MPa can be maintained, which still meets the application requirements of the forged Ti–6Al–4V alloy.

Ti6Al4V is widely used in aerospace and medical applications, where high demands on dimensional accuracy and surface quality require the application of post-processing to achieve optimal performance. However, the surface quality of parts fabricated by LPBF is inferior due to the inherent defects of LPBF. Therefore, it is important to investigate the effect of post-processing on the surface quality of Ti6A14V parts fabricated by LPBF. In this work, the effect of post-processing methods (i.e., sandblasting, electrolytic polishing, chemical polishing, and abrasive flow polishing) on the surface quality of Ti6Al4V fabricated by laser powder bed fusion (LPBF) additive manufacturing was investigated. The changes in surface roughness and morphology of the 45° inclined square and curved pipe Ti6Al4V samples processed with post-processing were observed, and the weight and elemental changes of the parts were also analyzed. The result reveals that sandblasting, electrolytic polishing, chemical polishing, and abrasive flow polishing are all effective in improving the surface quality of Ti6Al4V parts fabricated by LPBF. The effect of sandblasting is mainly caused by sharp-edged grit driven by high-speed airflow, resulting in the lowest surface roughness and the least influence on the weight, but may contaminate the surface with residual brown corundum. Electrolytic polishing and chemical polishing achieve surface quality improvement through different corrosion patterns without changing the surface composition. The surface smoothness of parts processed with chemical polishing is the best, while the weight loss rate of the sample processed with electrolytic polishing is the most at about 7.47%. Abrasive flow polishing presents a remarkable effect on polishing the internal surface of the Ti6Al4V sample by the extrusion scratching, extrusion deformation, and micro-cutting effects of abrasive on the surface. The findings can provide important engineering references for the post-processing of precision Ti6Al4V parts fabricated by LPBF and further promote the engineering applications of Ti6Al4V parts.