We propose a light shutter device using dichroic-dye-doped liquid crystals (LCs) whose Bragg reflection wavelength is set to be infrared by controlling the pitch of cholesteric liquid crystals (ChLCs). A dye-doped long-pitch ChLC cell is switchable between the dark planar state and the transparent homeotropic state. It has the advantages of high transmittance, low operation voltage, and an easy fabrication process relative to previous LC light shutter devices. The proposed light shutter device is expected to achieve high visibility for transparent organic light-emitting diode displays and emerging smart windows, which can be used in airplanes, cars, and other similar applications.
We propose an optically and electrically switchable cholesteric liquid crystal (ChLC) cell doped with a push–pull azo dye. When the proposed ChLC cell is exposed to UV light, it is switched from the focal-conic to isotropic state by a cholesteric-isotropic phase transition through a trans–cis photo-isomerization of push–pull azo dye molecules. With removal of UV light, the ChLC cell will rapidly relax back to its initial state without exposure to a second light source that has a longer wavelength. We confirmed that the proposed optically and electrically switchable ChLC cell can be used as a smart window that can be switched on by applying sunlight or an electric field.
21 January 2021 in ACS Applied Materials & Interfaces
We propose a switchable achromatic reflector using a long-pitch cholesteric liquid crystal (CLC) whose Bragg reflection wavelength is chosen to be infrared by controlling the pitch of the CLC so that the planar texture is transparent over the entire visible wavelength. By using the light scattering of the focal conic texture, achromatic reflection can be achieved. Both textures are stable at zero electric field and the operating voltage of the proposed CLC device is much lower than that of conventional CLC devices. The proposed switchable reflector, which can be operated at a low voltage with low power, can be applied to reflective displays and to light shutters. By coupling with a reflective polarizer the efficiency of light scattering at the focal conic texture can be enhanced.
In this letter we demonstrate the vertical alignment of liquid crystal on inorganic thin film surfaces using the ion beam exposure. Nematic liquid crystal can be aligned vertically by the rotational oblique evaporation of thin films. However, the electro-optic switching behavior of liquid crystal along random directions results in disclination lines. By using the ion beam exposure, we can achieve highly uniform alignment without disclination lines. We found from x-ray diffraction and x-ray photoemission spectroscopy data that the vertical alignment can be achieved when approaches 1.5 at the film surface. We have shown that the pretilt angle can be controlled by changing ion beam parameters, such as the ion beam energy, the angle of incidence, and the exposure time. We also have shown that a liquid crystal cell aligned vertically by the ion beam exposure exhibits the voltage-transmittance curve similar to that of a rubbed polyimide cell.
We report a simple method for reducing the response time of a fringe-field switching liquid crystal cell by using two-dimensional confinement of the liquid crystals. Through both numerical calculations and experiments, we show that the switching speed can be increased by several fold in a fringe-field switching cell by simply using a rubbing angle of zero, which causes virtual walls to be built when an electric field is applied between the interdigitated electrodes and the common electrode, without requiring additional fabrication steps or complicated drive schemes. Furthermore, the devices fabricated with this method exhibit a reduced color shift and excellent dynamic stability, even with a high applied voltage and under external pressure.