Graphene oxide (GO) has been widely utilized as the precursor of graphene (GR) to fabricate GR-based hybrid photocatalysts for solar-to-chemical energy conversion. However, until now, the properties and roles that GO played in heterogeneous photocatalysis have remained relatively elusive. In this Review, we start with a brief discussion of synthesis and structure of GO. Then, the photocatalysis-related properties of GO, including electrical conductivity, surface chemistry, dispersibility, and semiconductor properties, are concisely summarized. In particular, we have highlighted the fundamental multifaceted roles of GO in heterogeneous photocatalysis, which contain the precursor of GR, cross-linked framework for constructing aerogel photocatalyst, macromolecular surfactant, two-dimensional growth template, and photocatalyst by itself. Furthermore, the future prospects and remaining challenges on developing effective GO-derived hybrid photocatalysts are presented, which is expected to inspire further research into this promising research domain.

GR and Ni₂P dual cocatalysts modified ZnIn₂S₄ nanoflower has been prepared and they can simultaneously utilize photogenerated electrons and holes to actuate the oxidation of benzyl alcohol (BA) to benzaldehyde (BAD) integrated with H₂ evolution.

Photocatalysis, as an inexpensive and safe technology to convert solar energy, is essential for the efficient utilization of sustainable renewable energy sources. Earth-abundant cobalt sulfide-based composites have generated great interest in the field of solar fuel conversion because of their cheap, diverse structures and facile preparation. Over the past 10 years, the number of reports on cobalt sulfide-based photocatalysts has increased year by year, and more than 500 publications on the application of cobalt sulfide groups in photocatalysis can be found in the last three years. In this review, we initially summarize the four common strategies for preparing cobalt sulfide-based composite materials. Then, the multiple roles of cobalt sulfide-based cocatalysts in photocatalysis have been discussed. After that, we present the latest progress of cobalt sulfide in four fields of photocatalysis application, including photocatalytic hydrogen production, carbon dioxide reduction, nitrogen fixation, and photocatalytic degradation of pollutants. Finally, the development prospects and challenges of cobalt sulfide-based photocatalysts are discussed. This review is expected to provide useful reference for the construction of high-performance cobalt sulfide-based composite photocatalytic materials for sustainable solar-chemical energy conversion.