Magneto-plasmonic Ag/Ni and Ag/Fe nanoparticles (NPs) were synthesized in this work using the environmentally safe and contaminant-free dual-pulsed Q-switched Nd:YAG 1064 nm laser ablation method. The optical and magnetic characteristics of synthesized nanomaterials were investigated using a vibrating sample magnetometer and an ultraviolet-visible absorption spectrometer. According to transmission electron microscopy (TEM), the shape of Ag/Ni and Ag/Fe NPs seems to be spherical, with mean diameters of 7.3 nm and 11.5 nm, respectively. X-ray diffraction (XRD) was used in order to investigate and describe the phase structures of the synthesized nanomaterials. The synthesized NPs reached maximum temperatures such as 48.9, 60, 63.4, 70, 75, and 79 °C for Ag/Ni nanofluid and 52, 56, 60, 68, 71, and 72 °C for Ag/Fe nanofluid when these nanofluids were subjected to an NIR 808 nm laser with operating powers of 1.24, 1.76, 2.36, 2.91, 3.5, and 4 W, respectively. Because of the plasmonic hyperthermia properties of nanoparticles, nanofluids display higher temperature profiles than pure water. According to these findings, plasmonic nanoparticles based on silver might be used to treat hyperthermia.
The wide variety of uses for nanoparticles (NPs) is due to their unique combination of features in a single assembly. The arc melted copper-cobalt ingot sample were qualitatively studied using laser induced breakdown spectroscopy (LIBS). Later, using the fabricated alloy as a target material for Nd:YAG laser ablation, CuCo2O4 NPs were synthesized. The magnetic properties of the synthesized NPs were studied using a vibrating sample magnetometer (VSM). To determine the composition and morphology of the synthesized NPs, X-ray diffraction (XRD), energy dispersive X-ray (EDX) analysis, transmission electron microscopy (TEM), scanning electron microscopy (SEM), and dynamic light scattering (DLS) techniques were used. The TEM and DLS showed that particles were spherical in shape with an average size of 32 nm and 28 nm, respectively. The antibacterial activity of the synthesized NPs was studied against S. aureus and E. coli strains as positive and negative controls using a standard approach. CuCo2O4 nanoparticles exhibited non-mutagenic potential against S. typhimurium TA-98 and TA-100 strains. Furthermore, the magnetic hyperthermia study of CuCo2O4 nanofluid was examined using a lab-made apparatus. The specific absorption rates (SAR) of 4.57 and 5.17 W/g were determined for the magnetic field strength of 230 μT and 247 μT, respectively. The study shows antibacterial activity and magnetic hyperthermia potential of the synthesized nanoparticles.
20 August 2024 in International Journal of Thermal Sciences
A hydrophone is used to detect the acoustic emission for the combined pulsed laser (CPL)-BK7 glass interaction. The CPL is composed of a nanosecond (ns) laser and a millisecond (ms) laser, which are separated with a certain period of time. Owing to the material defects affected mechanism, fluctuations are observed for the transmission time and the intensity of the acoustic emission during the ns laser interaction period. A weak and a strong acoustic emissions with spectrums dominated in the ranges of 10kHz∼60kHz and less than 8kHz, respectively, are detected during the remaining millisecond laser irradiation period. The two different behaviors of the acoustic emission are analyzed together with the evolution of the plume emission captured by the high speed camera during the laser irradiation and the ablated morphology on the sample. Results show that the high-frequency acoustic signal arises from a weak interaction process that a short lifetime plume emission and a shallow pit at the sample surface are observed. While the low-frequency acoustic signal is associated with a strong interaction process that an intense plume emission and a conical shaped cavity are detected. The consistent behaviors for the acoustic emission, the plume emission and the ablated size in dependence on the delay make the acoustic signal detection a reliable method in monitoring the CPL-BK7 glass interaction process and estimating the ablation results.