A lignin-based resin (LB) was used to improve the performance of soy flour-based adhesives. Soy flour (SF), polyamidoamine-epichlorohydrin (PAE), and LB were used to develop a plywood adhesive. The solid content and viscosity of the adhesive, the functional groups, the thermo-stability, and the crystallinity of the cured adhesives were characterized, and the performance of the resultant adhesive was evaluated by fabricating three-ply plywood. Results showed that the LB and PAE mixture used to modify the SF adhesive improved both dry and wet bond strength by 66.3% and 184.2%, respectively. Therefore, the PAE improved the wet bond strength, and the LB improved the dry bond strength. The improvement was attributed to: (1) the reaction of LB/PAE with the functions of the soy protein to form a cross-linking network; (2) a polycondensation reaction between the LB molecules improved the crosslinking density of the adhesive to form an interpenetration structure with cross-linked proteins; and (3) the easy penetration of the LB into the wood surface that enhanced interlocking between the wood and adhesive. Furthermore, the denser structure created by the LB and the PAE mixture improved thermal stability and decreased the crystallinity of the cured adhesive. The use of the LB and the PAE mixture increased the solid content by 35.5%, while still making its viscosity acceptable for industrial applications.

Wooden structures in China’s ancient buildings hold highly historical and cultural values. There is an urgent need to repair and replace the damaged wooden structures after hundreds and thousands of years of exposure to weather. Unfortunately, to date there is still a lack of insightful understanding on how the chemical structure, composition, and micro-morphology evolve over the long-term natural aging before artificial ancient timbers can be developed. This work aims to systematically examine the outer surface, middle layer, and inner surface of the same piece of Chinese fir (Cunninghamia lanceolate) collected from an ancient Chinese building. Based on qualitative and quantitative analysis, both cellulose and hemicellulose in aged woods are found to experience significant degrees of degradation. The crystalline regions of cellulose are also determined to undergo moderate degradation as compared to the control fresh wood. In comparison, the lignin basically remains unchanged and its content in the inner layer slightly increases, as evidenced by more free phenol groups determined. Relative to the outer and inner layer, the middle layer of the ancient wood shows the lowest degree of degradation close to that of the fresh wood. This work offers guidelines for fabricating artificial ancient woods to repair the destroyed ones in China’s ancient architectures.

The main objective of this work is to analyse the influence of heat treatment with polydimethylsiloxane on integrated performance of bamboo timber. Bamboo timber was heat treated using polydimethylsiloxane as a medium at 120, 150, 180 and 210 °C for 3 h in this study. Results revealed that the equilibrium moisture content (EMC) and linear swelling ratio of heat-treated bamboo specimens was remarkable decreased with increasing heat treatment temperature. The surface contact angle of water on the bamboo specimens was observed to increase with the increasing heat treatment temperature, indicating the reduction of wettability with water. Additionally, the modulus of rupture (MOR) and modulus of elasticity (MOE) was decreased with the increasing heat treatment temperature and lower than that of untreated specimens. Cellulose crystallinity of bamboo specimens was slightly decreased with the increase of heat treatment temperature. TG-DTG results illustrated a reduction in relative content of hemicellulose, and increase in relative content of lignin and cellulose of bamboo specimens with the increase of heat treatment temperature. Presence of the stretching vibration Si–C in Si–CH₃ indicated the bonding of siloxane to bamboo timber by forming covalent bonds. The colour of the heat-treated bamboo timber was even deepened after heat treatment, endowing the bamboo timber with better surface decoration performance.

As a natural polymer material, bamboo is regarded as a super material with lightweight but excellent mechanical properties. With the increasing application of bamboo in structures, high-strength composite materials, bridges, musical instruments, and damping materials, the study of Poisson’s ratio is of great significance to the structural design and stability of these materials. In this work, Poisson’s ratio of bamboo for different ages, growth heights, and bamboo wall radial positions were determined by electrical measurement. The relationships between intrinsic factors (density, chemical composition, crystallinity, and microfibril angle) and Poisson’s ratio were also analyzed. The results showed that Poisson’s ratio of bamboo for different ages and locations ranged from 0.180 to 0.334, decreased with the increasing bamboo age, growth height, and the radial position from the outer layer to the inner layer. While the peak values of Poisson’s ratio were obtained at bamboo of 2 years old, lower growth height, and near the outer layer of the bamboo. Furthermore, the Poisson’s ratio had a positive correlation with the increasing density, cellulose content, and MFA, but a negative correlation with lignin content. There is no direct relationship between the crystallinity and Poisson’s ratio, but it affects the axial and transverse deformation of bamboo, which can be used as an indirect index to judge Poisson’s ratio.