The photonic color-changing function of chameleons can be achieved by bionic soft-active photomechanochemically responsive cholesteric liquid crystal elastomers.
This investigation is the first report of an optically stable and tunable laser using a quantum-dot (QD) embedded cholesteric liquid crystal (QD-CLC) microresonator with an added chiral-azobenzene moiety. The QD nanocrystal, CLC, and chiral-azobenzene play key roles in the highly stable fluorescence nano-emitter, microresonator, and photo-tuner in the photonic bandgap (PBG) of the CLC and associated lasing output, respectively. Experimental results show that both the PBG and lasing emission of the QD-CLC composite sample can be reversibly tuned under successive irradiation with UV and blue beams. The all-optical tunability of the laser is attributed to the successive elongation and shrinkage of the CLC pitch induced by UV- and blue beam-irradiation induced trans–cis and cis–trans back isomerizations of chiral-azobenzene, respectively. In addition, this composite laser has a high damage threshold (>85 μJ per pulse), and thus shows a uniquely high optical stability. This work has successfully opened up an opportunity for developing QD coherent light sources or lasers with good optical stability and tunability (e.g., optically stable and tunable single photon lasers).
This investigation elucidates for the first time electrically controllable random lasers below the threshold voltage in dye-doped liquid crystal (DDLC) cells with and without adding an azo-dye. Experimental results show that the lasing intensities and the energy thresholds of the random lasers can be decreased and increased, respectively, by increasing the applied voltage below the Fréedericksz transition threshold. The below-threshold-electric-controllability of the random lasers is attributable to the effective decrease of the spatial fluctuation of the orientational order and thus of the dielectric tensor of LCs by increasing the electric-field-aligned order of LCs below the threshold, thereby increasing the diffusion constant and decreasing the scattering strength of the fluorescence photons in their recurrent multiple scattering. This can result in the decrease in the lasing intensity of the random lasers and the increase in their energy thresholds. Furthermore, the addition of an azo-dye in DDLC cell can induce the range of the working voltage below the threshold for the control of the random laser to reduce.
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A liquid crystal elastomer (LCE) film is successfully deposited with a terahertz metamaterial using thermal evaporation via a programmed electronic shutter and high-efficiency cooling system. The transmittance of the metamaterial at its resonance frequency is monotonically increased from 0.0036 to 1.0 as a pump beam bends the LCE film, so the metamaterial has a large switching contrast of 277 at the frequency. The monotonic increase in the resonance transmittance arises from the constant resonance frequency of the metamaterial at the transmittance modulation and depicts that the metamaterial-deposited LCE film can continuously tune the transmitted intensity of a terahertz beam. The metamaterial-deposited LCE film has potential in developing continuously tunable intensity modulators with large switching contrasts for the application of terahertz imaging and terahertz communication. Therefore, the thermal evaporation expands the application of metamaterials and improves their optical properties.