Chitosan, which is a derivative of chitin, is particularly popular due to its biodegradable and renewable nature. However, the properties of chitosan can be inconsistent due to the extraction process and its natural origin, which poses a challenge to its use in composite materials as a matrix. The properties of chitosan can be tuned by controlling the degree of deacetylation (the extent to which acetyl groups are removed from chitin to form chitosan) and molecular weight. This paper presents a detailed study on the extraction and characterization of chitosan from shrimp shells. The structural thermal and mechanical characterization were studied using several techniques: Fourier-transform infrared spectroscopy, X-ray diffraction, thermogravimetric analysis and differential scanning calorimetry. The intrinsic viscosity and deacetylation degree were determined using various methods. The results showed an average degree of deacetylation of 77%. The chitosan films exhibited a high tensile strength of 43.9 MPa and an elongation at break of 3.14%. The thermal analysis revealed that the films had a glass transition temperature of 88 °C and a maximum thermal degradation temperature of 320 °C. The findings of this research could contribute to the development of chitosan-based materials with improved properties, leading to its wider adoption in the future for composite matrix application. The simple and efficient method used for the extraction and purification of chitosan from shrimp shells makes it a cost-effective and eco-friendly alternative to synthetic polymers.

The growing demand for sustainable and self-powered technologies in automotive applications has led to increased interest in energy harvesting from vehicle suspensions. Recovering mechanical energy from road-induced vibrations offers a viable solution for powering wireless sensors and autonomous electronic systems, reducing dependence on external power sources. This study presents the design, modeling, and experimental validation of a hybrid energy-harvesting system that integrates piezoelectric and magnetoelectric effects to efficiently convert mechanical vibrations into electrical energy. A model-based systems engineering (MBSE) approach was used to optimize the system architecture, ensuring high energy conversion efficiency, durability, and seamless integration into suspension systems. The theoretical modeling of both piezoelectric and magnetoelectric energy harvesting mechanisms was developed, providing analytical expressions for the harvested power as a function of system parameters. The designed system was then fabricated and tested under controlled mechanical excitations to validate the theoretical models. Experimental results demonstrate that the hybrid system achieves a maximum power output of 16 µW/cm² from the piezoelectric effect and 3.5 µW/cm² from the magnetoelectric effect. The strong correlation between theoretical predictions and experimental measurements confirms the feasibility of this hybrid approach for self-powered automotive applications.

In the context of autonomous environmental monitoring, this study investigates a surface acoustic wave (SAW) sensor designed for selective carbon dioxide (CO₂) detection. The sensor is based on a LiTaO₃ piezoelectric substrate with copper interdigital transducers and a polyetherimide (PEI) layer, chosen for its high electromechanical coupling and strong CO₂ affinity. Finite element simulations were conducted to analyze the resonance frequency response under varying gas concentrations, film thicknesses, pressures, and temperatures. Results demonstrate a linear and sensitive frequency shift, with detection capability starting from 10 ppm. The sensor’s autonomy is ensured by a piezoelectric energy harvester composed of a cantilever beam structure with an attached seismic mass, where mechanical vibrations induce stress in a piezoelectric layer (PZT-5H or PVDF), generating electrical energy via the direct piezoelectric effect. Analytical and numerical analyses were performed to evaluate the influence of excitation frequency, material properties, and optimal load on power output. This integrated configuration offers a compact and energy-independent solution for real-time CO₂ monitoring in low-power or inaccessible environments.

A lead-free piezoelectric ceramic, Bismuth titanate (Bi₄Ti₃O₁₂), is synthesized as an environmentally friendly alternative to the commonly used Lead Zirconate Titanate (PZT). This study focuses on investigating the effects of processing conditions on the morphological and structural properties of piezoelectric ceramics. The material is synthesized successfully through a solid-state reaction technique and is fully characterized using various techniques, including XRD, Raman, TG/DTG, SEM/EDX, piezoelectric, and dielectric analysis. The results show that wet or dry milling affects the morphological properties of the piezoelectric ceramic powder. SEM images reveal that the ceramic prepared by solvent-assisted solid-state (BTOS) exhibits a crystallite length of about 2 micrometers, compared to the ceramic powder prepared in a dry medium (BTO), which shows a crystallite length of about 9 micrometers. The d₃₃ piezoelectric coefficient values are around 27.7 pC/N and 21.4 pC/N, and the Kp values are found to be 29% and 26% for BTOS and BTO, respectively. This work contributes to the optimization of lead-free piezoelectric ceramic processing with potential applications in various sectors.

The development of sustainable insulation materials plays a crucial role in creating energy-efficient and environmentally responsible buildings. This study investigates eco-friendly composite materials based on plaster and wood shavings for insulation purposes. Incorporating wood shavings into plaster improves thermal insulation and mechanical behavior by enhancing porosity, reducing density, and improving bonding. As the wood shaving content increases from 5% to 15%, the thermal conductivity decreases from 0.252 W/mK to 0.099 W/mK, reflecting superior insulating performance. Concurrently, thermal resistance rises, showcasing enhanced insulation. The material also demonstrates increased flexibility, with the Young’s modulus decreasing at higher wood shaving proportions. Numerical simulations confirm these observations, indicating a 12 K temperature drop for composites with 15% wood shavings compared to a 6 K drop for pure plaster. This study suggests that an insulation thickness of 6–7 cm for the 15% composite strikes the optimal balance between performance and cost-efficiency. The findings underscore the potential of wood shavings to significantly enhance the thermal efficiency and mechanical adaptability of plaster composites, promoting sustainable and effective building insulation solutions.