Mine tailings have shown viability as the fine–grained layer in a capillary barrier structure for controlling acid mine drainage in a circular economy. Their saturated hydraulic conductivities (k_sat) under wetting–drying cycles and freeze–thaw cycles remain unexplored. In this study, modified tailings with a weight ratio of 95:5 (tailings/hydrodesulfurization (HDS) clay from waste–water treatment) and an initial water content of 12% were used. The k_sat of specimens was measured after up to 15 wetting–drying cycles, each lasting 24 h, with a drying temperature of 105 °C. The k_sat for wetting–drying cycles decreased from 3.9 × 10⁻⁶ m/s to 9.5 × 10⁻⁷ m/s in the first three cycles and then stabilized in the subsequent wetting–drying cycles (i.e., 5.7 × 10⁻⁷ m/s–6.3 × 10⁻⁷ m/s). Increased fine particles due to particle breakage are the primary mechanism for the k_sat trend. In addition, the migration of fines and their preferential deposition near the pore throat area may also promote this decreasing trend through the shrinking and potentially clogging–up of pore throats. This could be explained by the movement of the meniscus, increased salinity, and, subsequently, the shrinkage of the electrical diffuse layer during the drying cycle. Similar specimens were tested to measure k_sat under up to 15 freeze–thaw cycles with temperatures circling between −20 °C and 20 °C at 12 h intervals. Compared to the untreated specimen (i.e., 3.8 × 10⁻⁶ m/s), the k_sat after three freeze–thaw cycles decreased by 77.6% (i.e., 8.5 × 10⁻⁷ m/s) and then remained almost unchanged (i.e., 5.6 × 10⁻⁷ m/s–8.9 × 10⁻⁷ m/s) in subsequent freeze–thaw cycles. The increased fine grain content (i.e., 3.1%) can be used to explain the decreased k_sat trend. Moreover, the migration of fines toward the pore throat area, driven by the advancing and receding of ice lens fronts and subsequent deposition at the pore throat, may also contribute to this trend.

To limit the oxidation of waste rocks that originates from mining operations and the subsequent leaching of acidic solutions with high concentration of metal ions, a tailing–rock–clay triple layer capillary cover system was developed to prevent rainwater infiltration in humid climatic regions. The fine grained soil (FGS) layer consists of mine tailing and a hydrodesulfurization (HDS) clay from waste-water treatment with a 95:5 mass ratio. The coarse grained soil (CGS) layer consists of local waste rock granules with a size of 1–10 mm. Methyltrimethoxysilane (MTMS), an oxidation-inhibiting agent with strong hydrophobicity, was passivated on the rock grains to further reduce water infiltration and leaching of metal ions. Prototype-scale column tests were performed with matric suction and water content measurements under 680 min rainfall of 60 mm/h, the most severe annual precipitation case scenario for the Dexing Copper Mine (Jiangxi Province, China, 28.95° N, 117.57° E, humid climate). Both the uncoated and the coated covers exhibited zero leakage throughout the experiment. The passivation on rock granules in the coated cover increased the water entry value (WEV) of the CGS layer to −0.56 kPa. This led to a 15 mm water storage increment in the overlain FGS layer as compared to that in the uncoated cover, and induced lateral drainage (5% of the precipitation) in the FGS layer, which was not overserved in the uncoated cover. The concentrations of the leached Fe²⁺, Cu²⁺, Zn²⁺, Mn²⁺ and Mg²⁺ cations drained from the CGS layers of the uncoated cover were 0, 0.4, 0.8, 73.5, and 590.5 mg/L, which are all within the regulation limits of industrial discharge water standards. The concentrations of Cu²⁺, Mn²⁺ and Mg²⁺ cations drained from the coated CGS layer were reduced by 1–3 orders of magnitude. The abovementioned laboratory studies validated the water retention and leaching prevention abilities of the proposed three-layer capillary covers and the MTMS coating, which hold promises in engineering applications.