The durability of geopolymer concrete containing Ground Granulated Blast Furnace Slag (GGBS) and Rice Husk Ash (RHA), along with Lightweight Expanded Clay Aggregate (LECA), was investigated. Six different LWGPC mixtures were made with NaOH molarities of 8, 10, and 12M. For each molarity, two combinations of source materials were selected: 100% GGBS (G) and 80% GGBS with 20% RHA (RG). In all the mixtures, coarse aggregate was substituted with 35% LECA. LWGPC mixtures were exposed to 3% HCl, 5% MgSO4, and 3.5% NaCl for studying the durability properties. The test results demonstrate that 100% GGBS with 12M NaOH (12G) outperformed all other mixtures. The residual compressive strength of 12G mix LWGPC specimens after six months of exposure was found to be 86.4% in an acid environment, 90.6% in a sulfate environment, and 91.4% in a salt environment. The elemental composition analyzed using EDAX reveals that silica, alumina, calcium, and sodium are the predominant elements that form a dense microstructure with N-A-S-H, C-A-S-H, and C-S-H. Further, the inner properties of the specimens exposed to chemicals were examined using MATLAB R2023b and ImageJ 1.54f based on SEM images. The SEM image showed that the porosity of LWGPC specimens ranged from 0.5194 to 0.6748 µm, signifying an enhanced durability performance. The experimental results and microstructural analysis show that the LWGPC incorporating RHA and GGBS with LECA offers a superior performance, making it a promising solution for sustainable and durable construction.
An attempt was made in the present work to study the compressive strength and microstructure of geopolymer containing high calcium fly ash (HCFA) and silica fume. Concentration of sodium hydroxide solution 8M, 10M, 12M & 14M, liquid to binder ratio 0.5 and sodium hydroxide to sodium silicate ratio 2.5 were selected for the mixes. Geopolymer mortar test results indicated that the mix with 40% silica fume by the weight of HCFA yielded higher compressive strength under ambient curing. The XRD pattern typically shows the major portion of amorphous phase of geopolymer. The existence of C-A-S-H gel, N-A-S-H gel and hydroxysodalite gel products were observed through SEM which developed dense microstructure and thus enhanced strength of HCFA and silica fume geopolymer.
26 September 2017 in Archives of Civil Engineering
The present study examines some durability aspects of ambient cured bottom ash geopolymer concrete (BA GPC) due to accelerated corrosion, sorptivity, and water absorption. The bottom ash geopolymer concrete was prepared with sodium based alkaline activators under ambient curing temperatures. The sodium hydroxide used concentration was 8M. The performance of BA GPC was compared with conventional concrete. The test results indicate that BA GPC developes a strong passive layer against chloride ion diffusion and provides better protection against corrosion. Both the initial and final rates of water absorption of BA GPC were about two times less than those of conventional concrete. The BA GPC significantly enhanced performance over equivalent grade conventional concrete (CC).
India generates 759.02 million metric tons of coal ash annually. Part of that quantity is successfully utilized, and the remaining portion of the ash is discarded into a landfill. There also is a need to address pollution. Cement industries are responsible for 7% of global warming. Cement has been replaced entirely by thermal power plant waste, and bottom ash is used as a binder to overcome those issues. A few researchers have carried out strength characterization, but an extensive study needs to be carried out under different environmental exposures. Therefore, the present study investigated macro and micro properties of bottom ash geopolymer concrete (BAGPC) subjected to aggressive ecological exposure conditions such as acid, salt, and sulfate attack. Sodium silicate (Na2SiO3) and sodium hydroxide (NaOH) of eight molarities were used as activators for the bottom ash geopolymer concrete (BAGPC) binder. Further bonding between steel and conventional concrete BAGPC mixes was investigated. The durability of conventional concrete (CC) was taken as the control mix to compare the durability of the optimized mix (B4) of bottom ash geopolymer. The test samples were cured for 28 days under ambient temperature and tested for the effect of MgSO4, NaCl, and HCl. The strength loss and weight loss of the BAGPC B4 mix after 7, 28, 56, 90, and 180 days under aggressive conditions showed better performance than CC. It has been observed that geopolymer concrete has good bonding in nature, and the bond strength results indicate excellent bonding between steel and concrete. Microstructure studies revealed that the BAGPC B4 mix had a strong microstructure and not as much of a porous structure. It is concluded that BAGPC has potential value in the construction industry based on all aspects of the experiment.
The study aims the performance of presoaked light expanded clay aggregate (LECA) and fly ash aggregate (FAA) as partial replacement of river sand in self compacting concrete (SCC). On a volume basis, presoaked LECA and FAA partially replace river sand. LECA and FAA are presoaked for 24 hours before casting of SCC. The water retained in the lightweight aggregates (LWAs) pores acts as an internal curing reservoir. SCC workability characteristics, including as flowability, filling and passing capabilities, resistance to segregation, and concrete bleeding, were evaluated using slump cones, U-boxes, L-boxes, V-Funnels, and J-ring tests. Addition of LECA and FAA reduces the water for curing and also attain good workability and strength of SCC. The durability characteristics such as sulphate attack, acid attack are conducted in various durations like 7, 28, 56, 90, 180 days. Further, bond strength and accelerated corrosion tests also conducted. From all the mechanical and durability tests on SCC with LECA and FAA by 15% replacement for fine aggregate shows more beneficial effect in strength, microstructural and durability properties than those demonstrated by control mix concrete.