The results of studies on the ozone synthesis under discharges generated on the surface of the ceramic actuator built as the concentric-strip electrode system are presented. Experiments were carried out in pure oxygen. The ozonizer, in which the gas flows with variable linear velocity, was used. The ozone concentrations and the process energy efficiencies show the possibility of effective ozone generation in the reactors with nonconventionally organized discharge space.
3 August 2017 in Journal of Radioanalytical and Nuclear Chemistry
Flotation tailings from copper production are deposits of copper and other valuable metals, such as Mo, V and U. New hydrometallurgical technologies are more economical and open up new possibilities for metal recovery. This work presents results of the study on the extraction of copper by mixed extractant consisting p-toluidine dissolved in toluene. The possibility of simultaneous liquid–liquid extraction of molybdenum and vanadium was examined. D2EHPA solutions was used as extractant, and recovery of individual elements compared for the representative samples of ore and copper flotation tailings. Radiometric methods were applied for process optimization.
The extraction of useful minerals or geological materials from the Earth’s crust, most typically from various sources, is crucial to a country’s development and progress. Mineral-rich countries use these resources to transform their economies and propel them toward long-term prosperity. There is an urgent need for the world to increase mineral exploration efforts, improve the recycling of important metal-containing resources, and extract them using upgraded hydrometallurgical procedures with high recovery efficiency. This review paper highlights the importance of strategic and critical metals in the economy and the role of nuclear techniques in the analysis, process optimization, and remediation of metals using solvent extraction, adsorption, and chromatographic resins. Radiotracer analysis, X-Ray Fluorescence spectrometry (XRF), Neutron Activation Analysis (NAA), and X-Ray Diffraction (XRD) are appropriate for improving laboratory-based hydrometallurgical processes, with future technical and economic benefits. The development and installation of novel instruments to provide the real-time control of mining and mineral processing plants for improved control have the potential to aid in the recovery of a broad range of metals.
Nuclear power plants have the lowest life-cycle greenhouse gas emissions intensity and produce more electricity with less land use compared to any other low-carbon-emission-based energy source. There is growing global interest in Generation IV reactors and, at the same time, there is great interest in using small modular reactors. However, the development of new reactors introduces new engineering and chemical challenges critical to advancing nuclear energy safety, efficiency, and sustainability. For Generation III+ reactors, water chemistry control is essential to mitigate corrosion processes and manage radiolysis in the reactor’s primary circuit. Generation IV reactors, such as molten salt reactors (MSRs), face the challenge of handling and processing chemically aggressive coolants. Small modular reactor (SMR) technologies will have to address several drawbacks before the technology can reach technology readiness level 9 (TRL9). Issues related to the management of irradiated graphite from high-temperature reactors (HTR) must be addressed. Additionally, spent fuel processing, along with the disposal and storage of radioactive waste, should be integral to the development of new reactors. This paper presents the key chemical and engineering aspects related to the development of next-generation nuclear reactors and SMRs along with the challenges associated with them.
Nuclear energy can help stop climate change by generating large amounts of emission-free electricity. Nuclear reactor designs are continually being developed to be more fuel efficient, safer, easier to construct, and to produce less nuclear waste. The term advanced nuclear reactors refers either to Generation III+ and Generation IV or small modular reactors. Every reactor is associated with the nuclear fuel cycle that must be economically viable and competitive. An important matter is optimization of fissile materials used in reactor and/or reprocessing of spent fuel and reuse. Currently operating reactors use the open cycle or partially closed cycle. Generation IV reactors are intended to play a significant role in reaching a fully closed cycle. At the same time, we can observe the growing interest in development of small modular reactors worldwide. SMRs can adopt either fuel cycle; they can be flexible depending on their design and fuel type. Spent nuclear fuel management should be an integral part of the development of new reactors. The proper management methods of the radioactive waste and spent fuel should be considered at an early stage of construction. The aim of this paper is to highlight the challenges related to reprocessing of new forms of nuclear fuel.
Poland is actively exploring the application of nuclear power as a substitute for its present reliance on fossil fuels for the generation of heat and electricity. This change reflects a calculated attempt to reduce carbon emissions, diversify the nation’s energy sources, and enhance the sustainability of its energy infrastructure. However, the implementation of nuclear technology faces many challenges, such as radiation exposure, the production of radioactive waste, the off-site effects of nuclear accidents, and high capital costs. Addressing such nuclear-safety-related issues is crucial for nuclear technology’s successful deployment. An extended analysis of the “coal-to-nuclear” process in terms of its safety has to be performed. Therefore, this review paper covers multidisciplinary studies related to the rollout of nuclear energy in Poland. The first stage of this study was the identification of the key areas of analysis, which included (i) formal requirements and recommendations imposed by international and national organizations on the process of designing and operating nuclear power systems; (ii) potential nuclear hazards for the personnel working at a nuclear reactor unit and the local population; (iii) the applied solutions of the security systems of a reactor itself, the steam turbine cycle, and the auxiliary infrastructure; and (iv) the management of spent nuclear fuel and radioactive waste. This methodology, developed based on a review of the literature and international standards, was tested for the selected country—Poland.