Climate change is impacting the severity of water pollution, and polluted water bodies have an impact on climate change. Increased precipitation and atmospheric temperature changes affect the flow of water bodies, causing interactions in the chemical kinetics of the contaminants present in water that should not be present in the first place. Likewise, anthropogenic activities and their waste management require urgent actions for the mitigation and adaptation to climate change. Fats, oils and grease (FOG) present in water are difficult to remove and affect the drinking water or wastewater treatment trains; that is, FOG can aggregate and clog subsequent operations and are susceptible to temperature changes. Relevant advances in FOG removal using oleic acid as a model compound submitted to a liquid–liquid extraction under menthol:lactic acid deep eutectic solvent (DES) mixture is presented.
1 October 2019 in Journal of Environmental Chemical Engineering
This work explores the technical viability in the use ofMoringa oleifera Lam. seeds produced in Ecuador as an adsorbent medium for copper (Cu), nickel (Ni) and chromium (Cr) present in water that could be implemented in future Water Resource Recovery Facilities in Ecuador. The seeds were prepared following a sequence of washing, drying, crushing, sieving, rewashing, and final drying. Two treatments were performed based on particle size. Treatment 1 consisted on a mixture of 70% of particles larger than 2 mm and 30% of particles between 1 and 2 mm; while Treatment 2 consisted only on 1 - 2 mm particles. Batch experiments were performed with metal concentrations ranging from 10 to 150 ppm, a dose of 1.00 g of MO per liter, and mechanical stirring for 1 hour. Treatment 2 showed to be more favorable to metal removal and the Langmuir model better characterized adsorption of the three metals.The best kinetic description of the three metals is that of a pseudo first-order reaction where the adsorption capacities are 50.93 mg Cu/g MO, 30.14 mg Ni/g MO, and 40.98 mg Cr/g MO, with removal percentage of 37 - 53 %, 39 - 76%, and 11 - 33%, respectively.