Plasma-activated water (PAW) is a liquid enriched with reactive oxygen and nitrogen species (RONS), which impart antimicrobial and bioactive properties. In this study, PAW generated in liquid or gas phase under nitrogen or oxygen atmospheres was characterized in terms of pH, electrical conductivity, oxidation-reduction potential, surface tension, and concentrations of H₂O₂ and NO₂⁻. Hydroxyl radical (•OH) formation was confirmed using DIPPMPO as a spin-trapping probe, while antioxidant activity was determined directly in treated water for the first time. The stability of reactive species was assessed over three months at room temperature, 4 °C, and −18 °C. Results indicate that plasma effects on physicochemical parameters depend strongly on the process gas. From a long-term storage perspective, samples maintained at 4 °C stabilized at higher H₂O₂ and NO₂⁻ concentrations. Antioxidant activity persisted for up to 60 days, though at low levels. EPR analysis revealed that hydroxyl radical concentration increased slightly during storage, with 60-day samples showing higher signal intensities compared to fresh PAW. Overall, the findings provide new insights into PAW composition, radical dynamics, and stability, highlighting the influence of gas atmosphere and storage conditions on its properties and supporting its potential for applications in the food, agriculture, and biomedical sectors.

This paper investigates the possibility of integrating the combination of nanofillers, titanium dioxide (TiO₂) and carbon nanotubes (CNT) into the thermoplastic polymer matrix. This combination of fillers can possibly modify the physico-chemical properties of composites compared to the pure polymer matrix. The composites were blended using the extrusion method. The composite filament produced was used to manufacture static mixers on a 3D printer using the additive manufacturing technology fused filament fabrication (FFF). The aim of this work was to inspect the influence of the filler addition on the thermal and mechanical properties of glycol-modified polyethylene terephthalate (PET-G) polymer composites. The fillers were added to the PET-G polymer matrix in several ratios. Tensile test results showed an increase in the overall strength and decrease in the elongation at break of the material. Melt flow rate (MFR) showed a decrease in the viscosity with the initial filler addition and reaching a plateau after 2 wt% filler was added. Differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA) showed minor changes in the thermal properties. Scanning electron microscope (SEM) results showed homogenous distribution of the filler in the matrix and strong filler–matrix adhesion. The results indicate suitable properties of new functional composites for the 3D printing of static mixers for application in tubular reactors.

The article discusses the importance of optimizing process parameters in 3D printing to achieve better mechanical properties of printed parts. It emphasizes the material extrusion 3D printing technology and some of the most commonly used materials, acrylonitrile butadiene styrene (ABS) and polyethylene terephthalate glycol (PETG). Optimizable process parameters such as, print angle, outer layer number, extruder flow ratio, extrusion (nozzle) temperature, and layer thickness are examined. The article also highlights the importance of postprocessing techniques, specifically thermal postprocessing (annealing) and chemical postprocessing in the acetone (AC) chamber, to enhance mechanical properties of printed parts. The results show that the wall structures played a crucial role in defining mechanical properties, acting as main load-bearing elements. Adjusted flow ratios influenced mechanical properties. Samples with a 25% extruder flow rate increase demonstrated a 44% rise in elongation at break, while a 50% increase led to slight strength reduction. The ABS material AC-treated sample exhibited 58.2% lower tensile strength and 1.9% lower elongation due to stress concentration, while thermally treated showed similar results to the default, printed at manufacturer-recommended settings. The PETG material AC-treated sample exhibited 53.2% lower tensile strength, but 17.5% higher elongation, while thermally treated showed similar results to the default. Samples printed at 0° orientation exhibited plastic deformation with the highest tensile strength and elongation, while samples at 45° and 90° orientations experienced delamination, leading to brittle fracture, proving that the orientation and interlayer adhesion have a great influence on mechanical properties. While the print settings and orientation had similar effects on mechanical properties of each material, postprocessing effects are greatly influenced by the polymer matrix.

Antibiotics present common pollution in the environment, and they are often found in surface waters. Their presence or decomposition in water under natural sunlight can cause different unwanted consequences on the environment. In this paper, we report the application of 3D printed photocatalysts shaped as helix static mixers for tentative photocatalytic oxidation of antibiotic amoxicillin. The research was carried out in laboratory conditions in a semi-pilot-scale compound parabolic reactor (CPC) with static mixers made from PETG with TiO₂ and MWCNT as fillers. The efficiency of 3D printed photocatalysts was evaluated in terms of amoxicillin decomposition kinetics using a pseudo-first-order kinetic model. The experimental results of amoxicillin decomposition and generated by-products were analyzed by using the Q-TOF LC/MS technique and presented using MassHunter Workstation.

The addition of static mixers within reactors leads to higher productivity of a process and an additional increase in mass and energy transfer. In this study, we developed millireactors with static mixers using stereolithography, an additive manufacturing technology. Computational fluid dynamics (CFD) simulations were conducted to study the flow, identify potential dead volumes, and optimize the design of the millireactors. We produced five millireactors with various static mixers and one tubular reactor without static mixers, which served as a reference. The Fenton reaction was performed as a model reaction to evaluate the performance of the millireactors. We observed that some of the reactors with static mixers had air plugs that created a significant dead volume but still exhibited higher conversions compared to the reference reactor. Our results demonstrate the potential of stereolithography for producing intricate millireactors with static mixers, which can enhance the productivity of chemical processes.