A.A.P.R. Perera

A.A.P.R. Perera

Department of Chemistry, Pittsburg State University, Pittsburg, California, USA
orcid

Research Focus & Metrics

Academic Career Length

5Years (2022-Present)

(Calculated once Scilit publication data is synced: current year − year of first publication + 1)

Representative Publications

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29 January 2023 in Materials
Verified
Journal Article
Open access
PDF file
APA.A.P.R. Perera
A.A.P.R. Perera
KMK.A.U. Madhushani
K.A.U. Madhushani
BPBuwanila Punchihewa
Buwanila Punchihewa
PKProf. Dr. Anuj Kumar
Prof. Dr. Anuj Kumar
Ram K. GuptaRam K. Gupta
Ram K. Gupta
MXene is becoming a “rising star” material due to its versatility for a wide portfolio of applications, including electrochemical energy storage devices, electrocatalysis, sensors, biomedical applications, membranes, flexible and wearable devices, etc. As these applications promote increased interest in MXene research, summarizing the latest findings on this family of materials will help inform the scientific community. In this review, we first discuss the rapid evolutionary change in MXenes from the first reported M2XTx structure to the last reported M5X4Tx structure. The use of systematically modified synthesis routes, such as foreign atom intercalation, tuning precursor chemistry, etc., will be further discussed in the next section. Then, we review the applications of MXenes and their composites/hybrids for rapidly growing applications such as batteries, supercapacitors, electrocatalysts, sensors, biomedical, electromagnetic interference shielding, membranes, and flexible and wearable devices. More importantly, we notice that its excellent metallic conductivity with its hydrophilic nature distinguishes MXene from other materials, and its properties and applications can be further modified by surface functionalization. MXene composites/hybrids outperform pristine MXenes in many applications. In addition, a summary of the latest findings using MXene-based materials to overcome application-specific drawbacks is provided in the last few sections. We hope that the information provided in this review will help integrate lab-scale findings into commercially viable products.

20 December 2022
Verified
Book Chapter
Closed access
PDF file
BPBuwanila Punchihewa
Buwanila Punchihewa
APA.A.P.R. Perera
A.A.P.R. Perera
FSFelipe M. de Souza
Felipe M. de Souza
RGRam K. Gupta
Ram K. Gupta
Over the past two decades, the application of polymers in the field of biomedicine has grown exponentially due to the special properties of some polymers such as their biocompatibility, non-toxicity, and biodegradability with outstanding physical and mechanical properties. Biocompatibility and biodegradation are very important for materials that are relevant to the field of biomedicine because the formation of toxins after their decomposition poses many critical problems, and the lack of biocompatibility hinders the desired function of the polymer. The massive development of polymers and the synthesis of multifunctional biomolecules have led to the replacement of old biodegradable materials used in biomedical applications with polymeric biomaterials. Synthesized polymers and naturally derived polymers can be applied to different sections of the biomedical field. In this chapter, the authors discuss the selected applications and advancements of synthesized polymers and naturally derived polymers in biosensors, bioelectronic devices, tissue engineering, and regenerative medicine.


15 December 2022
Verified
Book Chapter
Closed access
PDF file
APA.A.P.R. Perera
A.A.P.R. Perera
BPBuwanila Punchihewa
Buwanila Punchihewa
FSFelipe de Souza
Felipe de Souza
RGRam K. Gupta
Ram K. Gupta
Many countries are researching the use of renewable energy sources to mitigate global environmental damage. In recent years, one-dimensional (1D) structured materials have made major contributions to advanced energy applications due to their many unique properties. Current research is now focusing on 1D polymeric materials as alternative materials for green energy generation and storage devices. Firstly, this chapter discusses the fabrication of 1D polymeric materials using electrospinning, interfacial polymerization, sol-gel, and chemical vapor deposition methods for various energy applications. Secondly, the chapter details the use of 1D polymeric materials (fibers, wires, ribbons, and rods) to improve the efficiency of advanced power applications, with a specific focus on solar cells, fuel cells for energy generation, batteries, and supercapacitors for energy storage. Finally, a brief discussion on 1D polymeric materials for wearable devices is included.

20 December 2022
Verified
Book Chapter
Closed access
PDF file
APA.A.P.R. Perera
A.A.P.R. Perera
KMK.A.U. Madhushani
K.A.U. Madhushani
FSFelipe M. de Souza
Felipe M. de Souza
TDTim Dawsey
Tim Dawsey
RGRam K. Gupta
Ram K. Gupta
The use of low-cost bio-renewable materials for the development of value-added product s, including polyurethanes, is highly desired by many industries. Polyurethanes are generally synthesized by reacting polyols and isocyanates in the presence of catalysts, surfactants, and blowing agents. This chapter provides a detailed synthesis of a chicken fat-based polyol through epoxidation followed by a ring-opening approach to make rigid polyurethane foams (RPUF). The high flammability of RPUF is one of the major concerns, whether they are synthesized using petrochemical or biobased materials. To reduce the flammability of RPUF, dimethyl methylphosphonate (DMMP), a P-based flame retardant (FR) was introduced. The first section of this chapter provides a general introduction to polymers, their applications, and the market, particularly for polyurethanes (PUs). The second section discusses the common materials used for manufacturing PUs including petrochemical and renewable materials. Various biomaterials such as vegetable oils, essential oils, and a novel study based on polyol from chicken fat for polyurethanes are covered. The third section addresses the main techniques such as hydroformylation/reduction, ozonolysis/reduction, thiol-ene coupling, and epoxidation/ring-opening employed for the synthesis of bio-polyols. The fourth section presents a description of the PU foams using chicken fat-based polyol and FR. A detailed discussion in terms of the properties of the chicken fat-based PU is provided along with a comparison of its properties with other similar works. The last section provides some insights into the future perspectives for this area. This chapter aims to provide insight into the experimental design while introducing novel bio-based materials such as chicken fat as a sustainable option for polyurethane industries.