Volatile organic compounds (VOCs) are important precursors for the formation of secondary pollutants, such as fine particulate matter (PM) and ozone (O3), which will lead to severe atmospheric environmental problems to restrict the sustainable development of the social economy. Catalytic oxidation is a safe, eco-friendly, and simple method for eliminating VOCs, which can be converted into CO2 and H2O without the generation of other harmful substances. The fabrication and development of catalysts are very crucial to enhance the catalytic oxidation efficiency of the removal of VOCs. The noble metal catalyst is one of the commonly used catalysts for the catalytic oxidation of VOCs because of the high reaction activity, good stability, poisoning-resistant ability, and easy regeneration. In this review, the research progress of noble metal (Pt, Pd, Au, Ag, and Ir) catalysts for the removal of VOCs in recent years was summarized with the discussion of the influence factors in the preparation process on the catalytic performance. The reaction mechanisms of the removal of VOCs over the corresponding noble metal catalysts were also briefly discussed.
The catalytic dehydrogenation of propane to propene is an alternative technique to supplement the traditional steam cracking and catalytic cracking process for satisfying the continuously increasing demand for propylene downstream products. In this study, the parent PtSn/γ-Al2O3 catalyst was fabricated via the one-step method for the subsequent La post-modification to prepare the catalysts for propane dehydrogenation. The prepared and spent catalysts were characterized by X-ray diffraction (XRD), N2 adsorption–desorption, scanning electron microscope (SEM), NH3 temperature-programmed desorption (NH3-TPD), H2 temperature-programmed desorption (H2-TPR), and thermogravimetric (TG) analysis. The catalytic performance and characterization results demonstrated that the addition of La into the parent catalyst could significantly improve the catalytic performance of the prepared catalyst. Especially, the PtSn-La2.2 catalyst with the 2.2 wt.% La addition exhibited the stable and highest propylene selectivity (>84%) under the investigation time of 800 min. The introduced La exhibits the ability to adjust the textural properties of the obtained catalysts, curb the acidity of support, promote the reduction of Pt species, and reduce the carbon accumulation on the prepared catalysts.
9 November 2020 in Reaction Chemistry & Engineering
In this study, a novel Fe(II) porphyrin conjugated amino modified HMS catalyst was synthesized and characterized by BET, XRD, TEM, SEM, and UV-vis techniques. The catalytic oxidative desulfurization performance and the different reaction conditions in model oil were investigated. The results showed that the mentioned FeC4Pc catalysts which integrated the high surface area of carriers and the high catalytic capacity and accessibility of active components exhibited excellent catalytic activity and reusability. Under the optimized reaction conditions, the desulfurization rate reached 98.4% of model oil enriched with model sulfur compounds. A possible mechanism of the oxidative desulfurization on FeC4Pc-HMS catalysts was proposed, and our experimental results demonstrated that the catalyst has potential for other oxidative reactions.