In 0.95[0.94Bi_0.5Na_0.5TiO₃-0.06BaTiO₃]-0.05CaTiO₃ ceramics, the temperature T_S (dielectric permittivity shoulder at about 125 °C) represents a transition between two different thermally activated dielectric relaxation processes. Below T_S, the approximately linear decrease of the permittivity with the logarithm of frequency was attributed to the presence of a dominant ferroelectric phase. Above T_S, the permittivity shows a more complicated dependence of the frequency and Raman modes indicate a sudden increase in the spatial disorder of the material, which is ascribed to the presence of a nonpolar phase and to a loss of interaction between polar regions. From 30 to 150 °C, an increase in the maximum polarization with increasing temperature was related to three possible mechanisms: polarization extension favoured by the simultaneous presence of polar and non-polar phases; the occurrence of electric field-induced transitions from weakly polar relaxor to ferroelectric polar phase; and the enhanced polarizability of the crystal structure induced by the weakening of the Bi-O bond with increasing temperature. The occurrence of different electric field induced polarization processes with increasing temperature is supported by the presence of additional current peaks in the current-electric field loops.

Large ZT enhancement (50%) is obtained in hot forged nanostructured p-type Bi_0.5Sb_1.5Te₃ bulk alloys.