Here, we present a synthesis of three novel conjugated block-copolymers (BCP) with general formula P3HT-bridge-TBO, where P3HT is a poly(3-hexyl)thiophene, TBO is a thiophene-benzothiadiazole block, and the bridge is composed of two fluorene units (FF) or two thiophenes (TT) or a mixture (TF). It is demonstrated that the physicochemical properties of the materials with different bridges are similar. Furthermore, P3HT-bridge-TBO materials are investigated in PSCs with classical n-i-p configuration for the first time. PSCs with BCPs reach average efficiencies with a top of 14.4% for P3HT-FF-TBO. At the same time, devices demonstrate spectacular long-term operation stability after 1000 h under constant illumination with minor changes in efficiency, while PSCs with state-of-the-art hole-transport layer demonstrate unstable behavior. This groundbreaking work demonstrates the potential of BCP to ensure the stable operation of perovskite photovoltaics.