Raman spectroscopy has been used to study the ferroelectric tetragonal to paraelectric cubic phase transition in undoped (BT) and [where (BCT), Sr (BST), and Pb (BPT)]. In BT and BPT, mode characteristic of the tetragonal phase at 303 and persisted until above , indicating the presence of local dynamic polar clusters well above the displacive phase transitions, and , respectively. However, in BCT and BST, the Raman spectra exhibited only broad second order bands above , suggesting that Ca and Sr, -site dopants supress local dynamic polar clusters.
5 October 2009 in The Journal of Physical Chemistry C