Carbon dots are one of the most promising nanomaterials which exhibit a wide range of applications in the field of bioimaging, sensing and biomedicine due to their ultra-small size, high photostability, tunable fluorescence, electrical properties, etc. However, green carbon dots synthesized from several natural and renewable sources show some additional advantages, such as favorable biocompatibility, wide sources, low cost of production and ecofriendly nature. In this review, we will provide an update on the latest research of green carbon dots regarding their applications in cancer therapy and in the development of electrochemical sensors. Besides, the toxicity assessment of carbon dots as well as the challenges and future direction of research on their anticancer and sensing applications will be discussed.
3 September 2019 in ACS Sustainable Chemistry & Engineering
Polytetrafluoroethylene (PTFE) is probably the most extensively used chemically inert and thermally stable polymer. We report the degradation of polytetrafluoroethylene (PTFE) in water in presence of common metals and carbohydrates resulting in polymeric fragments. About 53 mg of solid materials consisting of polymeric fragments and copper were separated from a copper vessel in 15 days when a PTFE pellet of about 920 mg was stirred with 1000 ppm glucose in 70 mL water at 70 ˚C. Degradation produced fluorocarbon species in water, which were detected by high-resolution electrospray ionization mass spectrometry. Triboelectric charging of the PTFE surface during stirring and consequent interaction of the charged surface with the metal ions, brought to solution by carbohydrate-induced corrosion, is attributed to this phenomenon. We show that such a process can be extended to other polymers such as polypropylene. The study suggests important consequences of nanoplastics to environment and health, including impact of such chemistry to cooking.
A new instrument combining pulsed laser ablation and inert gas condensation for the production of nanopowders is presented. It is shown that various nanostructured materials, such as regular metallic, semiconducting, insulating materials, complex high entropy alloys, amorphous alloys, composites and oxides can be synthesized. The unique variability of the experimental set-up is possible due to the reproducible control of laser power (pulse energy and repetition rate), laser ablation pattern on the target, and experimental conditions during the inert gas condensation, all of which can be controlled and optimized independently. Microstructure analysis of the as-prepared composite and amorphous Ni60Nb40 nanopowders establishes the instrument's ability for the synthesis of materials with unique compositions and atomic structure. It is further shown that small variations of the synthesis parameters can influence materials properties of the final product, in terms of particle size, composition and properties. As an example, the laser power has been used to control the magnetic properties of amorphous Ni60Nb40 nanopowders. A few selected examples of the manifold possibilities of the new synthesis apparatus are presented in this report together with detailed structural characterization of the produced nanopowders.
28 November 2023 in Journal of Polymers and the Environment