Water pollution from dyes is a major environmental challenge, demanding advanced materials for efficient degradation. In this study, we synthesized iron oxide nanoparticles (IONPs) using an aqueous extract of Senegalia catechu leaves and evaluated their photocatalytic activity in methylene blue (MB) dye degradation under sunlight irradiation. The IONPs were characterized by UV-visible spectroscopy (UV–vis), Fourier Transform Infrared Spectroscopy (FT-IR), X-ray Diffraction (XRD), Scanning Electron Microscopy (SEM), and Energy Dispersive X-ray Spectroscopy (EDS). XRD pattern showed a highly crystalline structure with an average crystallite size of 34.7 nm, while SEM images revealed predominantly spherical particles with uneven surface texture. Photocatalytic efficiency exceeded 80% MB dye degradation after 120 min of sunlight exposure. Optimization of catalyst dose, pH, dye concentration, and other parameters is essential for maximizing degradation efficiency. The IONPs demonstrated reusability over four degradation cycles, retaining effective photocatalytic performance. This study underscores the potential of green-synthesized IONPs as eco-friendly photocatalysts for wastewater treatment and environmental remediation.

A laboratory-synthesized triblock copolymer poly(ethylene oxide-b-acrylic acid-b-styrene) (PEG-PAA-PS) was used as a template to synthesize hollow BaCO₃ nanoparticles (BC-NPs). The triblock copolymer was synthesized using reversible addition–fragmentation chain transfer radical polymerization. The triblock copolymer has a molecular weight of 1.88 × 10⁴ g/mol. Transmission electron microscopy measurements confirm the formation of spherical micelles with a PEG corona, PAA shell, and PS core in an aqueous solution. Furthermore, the dynamic light scattering experiment revealed the electrostatic interaction of Ba²⁺ ions with an anionic poly(acrylic acid) block of the micelles. The controlled precipitation of BaCO₃ around spherical polymeric micelles followed by calcination allows for the synthesis of hollow BC-NPs with cavity diameters of 15 nm and a shell thickness of 5 nm. The encapsulation and release of methotrexate from hollow BC-NPs at pH 7.4 was studied. The cell viability experiments indicate the possibility of BC-NPs maintaining biocompatibility for a prolonged time.

Iron oxide nanoparticles (IONPs) were synthesized via a block copolymer-assisted hydrothermal method and the phase purity and the crystal structure were investigated by X-ray diffraction. The Rietveld analysis of X-ray diffractometer spectra shows the hexagonal phase symmetry of α-Fe₂O₃. Further, the vibrational study suggests Raman active modes: 2A1g + 5Eg associated with α-Fe₂O₃, which corroborates the Rietveld analysis and orbital analysis of 2PFe. The superparamagnetic behavior is confirmed by magnetic measurements performed by the physical properties measurement system. The systematic study of the Congo red (CR) interaction with IONPs using a UV-visible spectrophotometer and a liquid chromatography–tandem mass spectrometry system equipped with a triple quadrupole mass analyzer and an electrospray ionization interface shows effective adsorption. In visible light, the Fe₂O₃ nanoparticles get easily excited and generate electrons and holes. The photogenerated electrons reduce the Fe³⁺ ions to Fe²⁺ ions. The Fe²⁺/H₂O₂ oxidizes CR by the Fenton mechanism. The strong adsorption ability of prepared nanoparticles towards dyes attributes the potential candidates for wastewater treatment and other catalytic applications.

This study reports on the fabrication of chitosan-zein films decorated with silver nanoparticles synthesized via a green and eco-friendly approach using an extract of Bergenia ciliata. The strong reducing ability and caping properties of the phytochemicals present in the extract enabled the formation of silver nanoparticles with an average diameter of ~40 nm without any external reducing agent and stabilizer. The uniformly distributed Ag nanoparticles were embedded in the chitosan-zein matrix. The structural and morphological characteristics of the film were analyzed via Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, X-ray diffractometry, scanning electron microscopy, and transmission electron microscopy. The silver nanoparticles decorated with chitosan-zein films showed thermal stability, durability, and excellent antimicrobial activities. This finding demonstrates a sustainable and green pathway for developing multifunctional nanocomposite films, contributing to the advancement of bio-based materials for prospective therapeutic applications and active food packaging.