In the face of smart and varied jamming, intelligent radar anti-jamming technologies are urgently needed. Due to the variety of radar electronic counter-countermeasures (ECCMs), it is necessary to efficiently optimize ECCMs in the high-dimensional knowledge base to ensure that the radar achieves the optimal anti-jamming effect. Therefore, an intelligent radar anti-jamming decision-making method based on the deep deterministic policy gradient (DDPG) and the multi-agent deep deterministic policy gradient (MADDPG) (DDPG-MADDPG) algorithm is proposed. Firstly, by establishing a typical working scenario of radar and jamming, we designed the intelligent radar anti-jamming decision-making model, and the anti-jamming decision-making process was formulated. Then, aiming at different jamming modes, we designed the anti-jamming improvement factor and the correlation matrix of jamming and ECCM. They were used to evaluate the jamming suppression performance of ECCMs and to provide feedback for the decision-making algorithm. The decision-making constraints and four different decision-making objectives were designed to verify the performance of the decision-making algorithm. Finally, we designed a DDPG-MADDPG algorithm to generate the anti-jamming strategy. The simulation results showed that the proposed method has excellent robustness and generalization performance. At the same time, it has a shorter convergence time and higher anti-jamming decision making accuracy.