Once petroleum hydrocarbons (PHs) are released into the soil, the interaction between PHs and soil media is dependent not only upon the soil properties but also on the characteristics of PHs. In this study, the key factors influencing the interactions between PHs and soil media are discussed. The key factors include: 1) the characteristics of PHs, such as volatility and viscosity; and 2) soil properties, such as porosity, hydraulic properties and water status, and organic matter; and 3) atmospheric circumstances, such as humidity and temperature. These key factors can be measured either ex-situ using conventional laboratory methods, or in situ using portable or handheld instruments. This study overviews the current ex/in situ techniques for measuring the listed key factors for PH contaminated site assessments. It is a tendency to apply in situ methods for PH contaminated site characterisation. Furthermore, handheld/portable Fourier transform infrared spectroscopy (FTIR) instrument provides tremendous opportunities for in-field PH contaminated site assessment. This study also reviewed the non-destructive FTIR spectroscopy analysis coupling with handheld FTIR for in-field PH contaminated site characterisation, including determining the concentration of total PH, dominant PH fractions and soil key properties for PH transport modelling.

Soil colour is one of the most important factors in agriculture for monitoring soil health and determining its properties. For this purpose, Munsell soil colour charts are widely used by archaeologists, scientists, and farmers. The process of determining soil colour from the chart is subjective and error-prone. In this study, we used popular smartphones to capture soil colours from images in the Munsell Soil Colour Book (MSCB) to determine the colour digitally. These captured soil colours are then compared with the true colour determined using a commonly used sensor (Nix Pro-2). We have observed that there are colour reading discrepancies between smartphone and Nix Pro-provided readings. To address this issue, we investigated different colour models and finally introduced a colour-intensity relationship between the images captured by Nix Pro and smartphones by exploring different distance functions. Thus, the aim of this study is to determine the Munsell soil colour accurately from the MSCB by adjusting the pixel intensity of the smartphone-captured images. Without any adjustment when the accuracy of individual Munsell soil colour determination is only $9\%$ for the top 5 predictions, the accuracy of the proposed method is $74\%$, which is significant.

Locating underground pipeline leaks can be challenging due to their hidden nature and variable terrain conditions. To sample soil gas, solid-phase microextraction (SPME) was employed, and a portable gas chromatography/mass spectrometry (GC/MS) was used to detect the presence and concentrations of petroleum hydrocarbon volatile organic compounds (pH-VOCs), including benzene, toluene, ethylbenzene, and xylene (BTEX). We optimized the extraction method through benchtop studies using SPME. The appropriate fibre materials and exposure time were selected for each BTEX compound. Before applying SPME, we preconditioned the soil vapour samples by keeping the temperature at around 4 °C and using ethanol as a desorbing agent and moisture filters to minimize the impact of moisture. To conduct this optimisation, airbags were applied to condition the soil vapour samples and SPME sampling. By conditioning the samples using this method, we were able to improve analytical efficiency and accuracy while minimizing environmental impacts, resulting in more reliable research data in the field. The study employed portable GC/MS data to assess the concentration distribution of BTEX in soil vapour samples obtained from 1.5 m below the ground surface at 10 subsurface vapour monitoring locations at the leak site. After optimization, the detection limits of BTEX were almost 100 µg/m³, and the measurement repeatabilities were approximately 5% and 15% for BTEX standards in the laboratory and soil vapour samples in the field, respectively. The soil vapour samples showed a hotspot region with high BTEX concentrations, reaching 30 mg/m³, indicating a diesel return pipeline leak caused by a gasket failure in a flange. The prompt detection of the leak source was critical in minimizing environmental impact and worker safety hazards.