Growing in Liquid: The ability to control the growth of materials at the nanometer scale is key to nanotechnology. Materials grown in liquids, however, are difficult to track on a particle-by-particle basis during growth. Two studies used an in situ liquid cell to follow the formation of larger nanoparticles or nanorods grown in solvents using high-resolution transmission electron microscopes.
Liao
et al. (p. 1011 ) watched platinum iron nanorods form from kinked chains of connected nanoparticles that gradually reoriented and straightened to form rigid rods.
Li
et al. (p. 1014 ) observed the coalescence of iron oxyhydroxide nanoparticles through an oriented attachment mechanism, whereby two similar particles rotated until their corresponding crystal lattices aligned.
Watching platinum nanocube growth: Size and shape drive the properties of metal nanoparticles. Understanding the factors that affect their growth is central to making use of the particles in a range of applications. Liao et al. tracked the growth of platinum nanoparticle shapes at high resolution using state-of-the-art liquid cells for in situ monitoring inside an electron microscope. The authors tracked changes in the growth rates at different crystal facets caused by differences in the mobility of the capping ligand. Science , this issue p. 916
5 November 2008 in Angewandte Chemie International Edition
We report direct visualization of electrochemical lithiation and delithiation of Au anodes in a commercial LiPF6/EC/DEC electrolyte for lithium ion batteries using transmission electron microscopy (TEM). The inhomogeneous lithiation, lithium metal dendritic growth, electrolyte decomposition, and solid–electrolyte interface (SEI) formation are observed in situ. These results shed lights on strategies of improving electrode design for reducing short-circuit failure and improving the performance of lithium ion batteries.