Macroscopic properties of sandstone are commonly attributed to the degradation of its microstructure during heating treatment processes. However, few previous studies have focused on comprehensive observations on how the microstructure of sandstone changes with temperature. In this study, a kind of sandstone containing quartz, albite, calcite, and laumontite (little), was collected from Linyi (Shandong Province, China) to observe the microstructure degradation changes with temperature by X-ray diffraction (XRD), Scanning electron microscopy (SEM) and thermo-gravimetric analyses (TGA). Firstly, 10 groups of sandstone samples were heated from 25 °C to 900 °C. Then, some core micro-parameters including lattice constant, full width at half maximum (FWHM), micro-strain, dislocation density, TGA curve changes and failure characteristic of the mineral were analyzed comprehensively. Finally, the underlying mechanism causing the microscopic thermal damage at different temperature intervals was also discussed. The results showed that: (1) quartz, the framework component of this sandstone, underwent an α- to β-phase change over the temperature range from 400 °C to 600 °C. This phenomenon caused the lattice constant, micro-strain, dislocation density and TGA curve to decrease sharply during this interval, leading to the microstructure deterioration of sandstone; (2) calcite underwent a decomposition reaction between 600 °C and 800 °C, and resulted in the XRD pattern peak, lattice constant, micro-strain and TGA curve dropping continuously. It destroyed further the internal microstructure of sandstone and produced numerous inter-granular cracks around quartz crystals; (3) further examination found that the decomposition reactions of minerals presented non-synchronized characteristics due to the different sensitivities of minerals to temperature, which led to thermal stress, thermal fracturing of minerals, and thermal reactions happening in different temperature intervals.

The loess landslide in Gaoling District of Xi’an, Shaanxi in China is closely related to the seasonal freeze–thaw cycle, which is manifested by the destruction of pore structure and strength deterioration of the loess body under freeze–thaw conditions. In order to study the relationship between macro-strength damage and pore structure deterioration of saturated loess under freeze–thaw conditions and its influence on the stability of landslides, this paper explores the effect of freeze–thaw cycles on the strength of saturated undisturbed loess through triaxial compression test, and explores the micro-microstructure changes of saturated undisturbed loess through scanning electron microscopy (SEM) and nuclear magnetic resonance (NMR). This is to analyze the evolution of the pore structure and strength loss evolution of saturated loess during the freeze–thaw process, and to describe the freeze–thaw damage of saturated undisturbed loess through the change of porosity and strength deterioration. Then, the internal correlation expression between the porosity change and the strength degradation is established to realize the verification analysis of the test data based on the correlation model. The research results show that: (1) As the number of freeze–thaw cycles increases, the peak strength loss rate gradually increases, and the strength deterioration of saturated loess becomes more and more obvious. (2) The freeze–thaw cycle will lead to the development of pores and cracks in the sample, accompanied by the generation of new cracks, which will cause the deterioration of the pore structure of the sample as a whole. (3) The response of strength damage and porosity deterioration of saturated undisturbed loess is roughly similar under the freeze–thaw cycle. The change in porosity can be measured to better reflect the strength deterioration of saturated loess. Therefore, the change of pore structure of undisturbed loess under freeze–thaw cycle conditions is tested by field sampling and indoor tests to reflect the phenomenon of strength deterioration, thereby analyzing the stability of loess slopes.

Spalling disease caused by freeze–thaw cycles often occurs on the loess cut-slopes in northern Shaanxi. The deterioration of the pore structure and mechanical strength of loess under a freeze–thaw environment is one of the critical reasons underlying the occurrence of spalling disease in the slopes. In order to explore the effects of freeze–thaw cycles on the pore structure and the mechanical strength of loess, four initial water contents (7%, 9%, 12%, and 14%) and six freeze–thaw cycles (zero, one, three, five, 10, and 20) were considered in this study. Nuclear magnetic resonance (NMR) and triaxial compression tests were carried out to analyze and reveal the mechanisms of effect causing the deterioration of the soil strength that affects the stability of loess cut-slopes. The results showed that the porosity growth increased with the initial water content and continued to increase during the freeze–thaw process until a later stage of the freeze–thaw cycle, when it gradually stabilized. The stress–strain curves were primarily influenced by the number of freeze–thaw cycles, the initial water content of the samples, and the confining pressure. Both the cohesion and the internal friction angle exhibited a decay law that showed a significant decrease, then a slow decrease, and finally stabilization during the freeze–thaw process. Small and micropores were predominant among the pore structures of the loess, while medium pores were the second most common, and large pores were the least common. With the increase in the initial water content, the pores transformed from micropore structures to medium and large pore structures. The soil strength deterioration was primarily driven by the phase changes of the pore water, as well as the water migration during the freeze–thaw process. This study will be beneficial for identifying the characteristics and types of freeze–thaw disease in cut-slope engineering in seasonally frozen loess areas and providing a theoretical reference and design basis for achieving green and sustainable development in slope engineering, management, and maintenance.