During its first two lunar day measurements, the visible and near‐infrared spectrometer onboard the Yutu‐2 Rover of the Chang’E‐4 mission acquired six in‐situ reflectance spectra from the floor of Von Kármán crater within the South Pole‐Aitken basin. A spectral lookup table search has shown that the regolith at the landing site contains 56%‐72% plagioclase, 9%‐28% orthopyroxene, 4% ‐19% clinopyroxene, and 2% ‐12% olivine, in relative abundance, in agreement with the results from Kaguya Multiband Imager mineral mapping. A mineral composition analysis using measurements made by the Moon Mineralogy Mapper and the Multiband Imager has shown that the surface materials of the landing site may have been ejected from the nearby Finsen crater. This result is also supported by principal component analysis which shows a strong correlation between the compositions of the landing area and Finsen crater.

The panorama cameras onboard the Yutu Rover of the Chang'E‐3 lunar mission acquired hundreds of high‐resolution color images of the lunar surface and captured the first in situ lunar opposition effect (OE) since the Apollo era. We extracted the phase curve and the color ratio in three bands with the phase angle range from 2° to 141°. Photometric inversions using the Hapke model reveal that submicroscopic dusts are present in the landing area and both the coherent backscattering and the shadow hiding are responsible for the strong OE. Compared with spaceborne measurements, the grains in the landing site are brighter, more transparent, and appear to be better crystallized than the average maria basaltic grains. The results show that the phase‐reddening effect appears to be present in the in situ phase curves. The current phase curve can be used as the ground‐truth validations of any future spaceborne phase curve measurement over the landing site region.

The visible and near‐infrared imaging spectrometer on board the Yutu Rover of Chinese Chang'E‐3 mission measured the lunar surface reflectance at a close distance (~1 m) and collected four spectra at four different sites. These in situ lunar spectra have revealed less mature features than that measured remotely by spaceborne sensors such as the Moon Mineralogy Mapper instrument on board the Chandrayaan‐1 mission and the Spectral Profiler on board the Kaguya over the same region. Mineral composition analysis using a spectral lookup table populated with a radiative transfer mixing model has shown that the regolith at the landing site contains high abundance of olivine. The mineral abundance results are consistent with that inferred from the compound measurement made by the on board alpha‐particle X‐ray spectrometer.

Laboratory spectrophotometric measurements of minerals common on the lunar surface (olivine, pyroxene, plagioclase, and ilmenite) are measured over a wavelength range of 0.4 to 2.5 μm to better understand the effects of the particle phase function (PF; P[g]) on the application of Hapke's radiative transfer model to reflectance spectra of lunar materials. One objective of this work is to determine if accounting for wavelength‐dependent photometric effects can improve spectral estimates of mineral abundance in lunar materials, particularly that of ilmenite. We also discuss a two‐step calibration method to correct for the non‐Lambertian behavior and wavelength dependence of the common reference standard Spectralon. Both a two‐term Legendre polynomial representation of the PF and the Henyey‐Greenstein PF are examined. We use our results to apply the Hapke radiative transfer model to reflectance spectra of lab mixtures and test the effects of different PF characteristics and assumptions. Laboratory spectra indicate that ilmenite exhibits more backward scattering behavior compared with silicate minerals, which are more forward scattering. We find that the variations in PF can affect derived single‐scattering albedo values and thus spectral unmixing results. Because single‐scattering contribution dominates the reflectance properties of dark minerals such as ilmenite, large uncertainties in derived single‐scattering albedo values can be introduced by small changes in PFs. However, it is observed that the use of a wavelength‐dependent PF does not produce significant differences in spectral unmixing results for binary and ternary silicate mixtures.

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Acquiring accurate visible and near-infrared (VisNIR) reflectance values of atmosphereless celestial bodies is very important in inferring the physical and geological properties of their surficial materials. When a calibration target with inherent non-trivial absorption features is used, the calibrated reflectance would essentially always contain spurious spectral features and the spectroscopic data may easily be misinterpreted if the artifact is not properly taken care of. We demonstrate with laboratory reflectance measurements that the VisNIR spectra of three typical planetary surface analog materials, lunar simulant JSC-1A, olivine and pyroxene grains, have an artificial peak at 2.1 µm when Spectralon-type plaque made of polytetrafluoroethylene is used as the calibration target in the NIR region. The degree of severity of this artifact is dependent on the strength of the 2.0 µm absorption feature of the mineral. Empirical methods are proposed to remove this artifact to bring the spectra close to that calibrated by a gold mirror which does not have any conspicuous absorption features in the NIR region. The correction methods may be applied to reflectance data acquired by the VisNIR imaging spectrometer onboard the Yutu Rover of the Chinese Chang’E 3 lunar mission which employed an onboard Spectralon-type calibration target.