Black carbon (BC), an important component of atmospheric aerosol, plays a significant role in regional climate, hydrological cycle, variation of monsoon rainfall, and human health. The 40-year detailed atmospheric BC over China from 1981 to 2020 is systematically investigated through the MERRA-2 reanalysis dataset. MERRA-2 BC generally showed a good correlation (R = 0.68) compared with 673 monthly samples from ground-based observation at 35 stations around China. The overall annual average of MERRA-2 BC concentration over China is 1.15 μg/m³, with a fast growth rate during 1981–2007 and a relatively slow decrease after that. The winter season has the highest mean concentration of BC, followed by autumn and spring, whereas summer shows relatively weaker values. The order of annual average BC concentrations during 1981–2020 is Beijing-Tianjin-Hebei region (BTH, 4.02 μg/m³) > Sichuan Basin (SB, 3.94 μg/m³) > Yangtze River Delta (YRD, 2.68 μg/m³) > Pearl River Delta (PRD, 1.47 μg/m³). The monthly mean BC concentrations over the BTH, YRD, PRD and SB are estimated to be smallest 3.18 μg/m³ in May, 1.94 μg/m³ in August, 0.82 μg/m³ in July, 3.04 μg/m³ in June, respectively, whilst largest consistently in December with 5.09 μg/m³, 3.83 μg/m³, 2.12 μg/m³, and 5.41 μg/m³, respectively. Our study indicates the primary potential source areas for BC are concentrated in the research city and its surroundings. Beijing and Chengdu are more BC-polluted areas than Shanghai and Guangzhou. Long-distance, regional transfer from south BTH contributes importantly to BC pollution in Beijing under the influence of prevailing southerly winds. The geographical location of Chengdu causes the transport and accumulation of BC inside the SB.

Black carbon (BC), particularly internally mixed and aged BC, exerts a significant influence on the environment and climate. Black carbon coated by non-absorbing materials shows an enhancement of BC absorption, whereas absorptive coatings on BC can reduce the BC absorption enhancement. In this paper we use the multiple-sphere T-matrix method to accurately model the influence of the absorbing volume fraction of absorbing coatings on the reduction of the absorption enhancement of partially coated BC. The reduction of the absorption enhancement due to the absorbing coating exhibited a strong sensitivity to the absorbing volume fraction of the coating, and no reduction of BC absorption enhancement was seen for BC particles with non-absorbing coatings. We found that coatings with higher absorbing volume fraction, greater coated volume fraction of BC, higher shell/core ratio, and larger coated BC particle size caused stronger reductions of the BC absorption enhancement, whereas the impact of the BC’s fractal dimension was negligible. Moreover, the sensitivity of the reduction of absorption enhancement resulting from the ratio of the absorbing coating shell to the BC core increased for coatings with higher absorbing volume fractions, higher coated volume fractions of BC, or larger particle sizes, although this effect was weaker than the sensitivities to size distribution, absorbing volume fraction of coating, and coated volume fraction of BC. Reductions in the absorption enhancements resulting from the absorbing coating for partially coated BC with various size distributions typically varied in the range of 0.0–0.24 for thin coatings with shell/core ratio of 1.5 and between 0.0 and 0.43 for thick coatings with shell/core ratio of 2.7. In addition, we propose an empirical formula relating the reduction of BC absorption enhancement to the absorbing volume fraction of the coating, which could inform a quantitative understanding and further applications. Our study indicates the significance of the absorbing volume fraction of coatings on the absorption properties of BC.

Radiation fog episodes are characterized by aerosol radiative properties measured at Hefei in urban central China, which hopefully benefits numerical weather prediction and air quality improvement for local governments. In this study, a high mean aerosol optical depth (AOD) is seen over Hefei during the sampling period, whereas an AOD of ~3.0 at 550 nm is observed during the fog episodes. We redefine the fog scavenging coefficient based on its starting and ending points in time, and a black carbon (BC) scavenging coefficient of 30% is observed. Meanwhile, the fog process cannot reduce aerosol number concentrations at size bins between 0.5 and 0.6 μm, whereas a mean particle scavenging coefficient of 21% at sizes within 0.6–1 μm is seen. Significantly large median aerosol scattering coefficient (2690 Mm⁻¹) and absorption coefficient (446 Mm⁻¹) at 550 nm, and low scattering Angstrom exponent in fog are observed, while distinctive particle size distributions between fog and haze are shown. Particle mean size distribution in fog is lower than that in haze at size bins between 0.7 and 2.1 μm, whereas the reverse is true for sizes within 0.5–0.7 μm and larger than 2.1 μm. Aerosol scattering during fog episodes undergoes a bigger increase than particle absorption, and this increase of scattering in fog is even higher than in haze. Median single scattering albedos of 0.86, 0.82, and 0.76 at 550 nm and aerosol radiative forcing efficiencies of −15.0, −14.0, and −10.0 W/m² are seen for fog, haze and clear periods, respectively, and more negative radiative forcing efficiency emphasizes the significance of fog episodes on climate forcing. Our study clearly reveals the changes of aerosol radiative properties during radiation fog, particularly a synchronous variation of fog aerosol backscattering ratio with the visibility, indicating that more large particles are formed with fog becoming thicker and are scavenged with the dissipation of fog.

The wet deposition flux of black carbon (BC) over the Sichuan Basin is studied on the basis of the MERRA-2 data from 1981 to 2020, aiming at investigating high BC wet deposition flux in China in terms of long-term spatial-temporal trends and influences of BC column mass density and precipitation. In China, the largest BC wet deposition flux with a regionally-averaged value of 1.00 × 10⁻² μg m⁻² s⁻¹ over the Sichuan Basin is observed, especially in the western and southern regions of the Basin with values as high as 2.20 × 10⁻² μg m⁻² s⁻¹. The seasonality of BC wet deposition flux over the Sichuan Basin depicts maximum levels in autumn, moderate levels in spring and winter, and minimum levels in summer. The monthly mean BC wet deposition flux varies almost twofold, ranging from the lowest average value of 8.05 × 10⁻³ μg m⁻² s⁻¹ in July to the highest 1.28 × 10⁻² μg m⁻² s⁻¹ in October. This study suggests that BC column mass density and precipitation are two significant factors affecting high BC wet deposition flux, whereas BC wet deposition flux is more related to BC column mass density than to precipitation over the Sichuan Basin.

Atmospheric dry deposition of black carbon (BC) is a significant but poorly understood and inadequately described process in aerosol-climate models. The 40-year detailed dry deposition velocities of hydrophilic BC over China from 1981 to 2020 were systematically studied based on the MERRA-2 reanalysis data, which hopefully will be beneficial for its applications in atmospheric systems for climate and air quality. The average dry deposition flux of hydrophilic BC over China was 0.00059 ± 0.00014 μg m⁻² s⁻¹, while its dry deposition velocity was estimated to be 0.00051 ± 0.00004 m s⁻¹. The monthly mean dry deposition fluxes of hydrophilic BC varied nearly 1.5 fold, ranging from the lowest 0.00046 ± 0.00011 μg m⁻² s⁻¹ in August to the highest 0.00068 ± 0.00019 μg m⁻² s⁻¹ in January. The spring season had the highest mean dry deposition flux of hydrophilic BC, followed by summer and winter, whereas autumn showed relatively weaker dry deposition flux. The mean dry deposition velocities of hydrophilic BC over the Beijing-Tianjin-Hebei region, Yangtze River Delta, Pearl River Delta and Tibet Plateau were estimated to be 0.00042 ± 0.00004, 0.00042 ± 0.00004, 0.00051 ± 0.00006 and 0.00078 ± 0.00005 m s⁻¹, respectively. The monthly and seasonal patterns of dry deposition velocities of hydrophilic BC differed from each other in different regions, and high air temperature or surface wind speed seemed to fortify dry deposition velocities of hydrophilic BC. Our study pointed to high dry deposition flux of hydrophilic BC in the northern China Plain and Sichuan Basin but large dry deposition velocities in the Tibet Plateau region.