Apatite Sr-Nd and zircon Hf-O isotopes are broadly used to trace magma sources and constrain magma evolution processes, further improving our understanding of the origin of granitoids. We present zircon U-Pb ages, whole-rock major and trace elements, and whole-rock Sr-Nd-Hf, zircon Hf-O, and apatite Sr-Nd isotopic data for the coarse-grained quartz monzonite, biotite monzogranite, and granite porphyry in the Yushulinzi pluton in the Liaodong Peninsula, the eastern North China Craton, to establish their magma sources and petrogenesis. The coarse-grained quartz monzonite, biotite monzogranite, and granite porphyry were formed contemporaneously, with zircon U-Pb ages of 123–119 Ma. They share enriched whole-rock Sr-Nd-Hf and zircon Hf isotopic compositions, and the coarse-grained quartz monzonite has crust-like δ¹⁸O values (5.7–6.7‰). The coarse-grained quartz monzonite and biotite monzogranite have variable apatite (⁸⁷Sr/⁸⁶Sr)_i ratios and negative apatite ε_Nd(t) values. These isotopic characteristics indicate that the different rock types in the Yushulinzi pluton were derived from the partial melting of ancient crustal material in the North China Craton. Their geochemical and petrographic characteristics indicate that the crystal-melt segregation model can be employed to elucidate the genetic links among different rock types, with the coarse-grained quartz monzonite representing crystal accumulation and the biotite monzogranite and granite porphyry representing interstitial melts extracted from a crystal-rich magma chamber. Furthermore, the variable apatite Sr isotopic compositions and subtle differences in the peak zircon ε_Hf(t) values of the studied rock samples confirm the possibility of a contribution from shallow crustal components and materials with high ε_Hf(t) values during magma evolution, which is not readily revealed by their whole-rock Sr-Nd-Hf isotopic compositions. These results demonstrate that in situ apatite Sr-Nd and zircon Hf-O isotopic analyses have the potential to provide distinctive insights into the magma sources and evolution of magmatic systems.

The South China Block had experienced a significant tectonic transition during the Mesozoic in response to the subduction of the Paleo- and the Pacific Ocean. Large-scale granitic intrusions with massive mineralization are widespread in South China, and their tectonic settings are not defined. The Xitian intrusion is ideal for probing the geodynamic setting and mineralization in South China because they comprise an abundance of microgranular enclaves (MEs) and diverse types of granite associated with mineralization. Age determined by zircon U-Pb dating suggests that the MEs and their host granites are coeval within error, of ca. 152 Ma. The MEs have a similar initial Hf-O isotopic composition as host granites, and the rapid cooling mineral textures indicate that they are autoliths. Geochemical data show that the host granites are high-K, calc-alkaline, and transitional from metaluminous to peraluminous, slightly enriched in light rare earth elements (LREEs) relative to heavy rare earth elements (HREEs), with obvious negative Eu anomalies, belonging to I-type. The Nb/Ta and Zr/Hf ratios indicate the volatile penetrates the magmatic-forming process, and the fluid with abundant volatile could extract metal element effectively from the mantle.

不同类型的岩浆岩可能来源于不同源区,经历复杂的岩浆演化过程,导致岩浆成分、温度和压力等条件发生变化。磷灰石在岩浆岩中广泛发育,可以形成于不同的岩浆环境。作为富含多种地球化学指示元素(如稀土元素、锶、锰及多种挥发分),并且对寄主岩浆环境的变化十分敏感的副矿物,近年来被广泛应用于岩浆岩和矿床成因等研究中。了解不同类型岩石中磷灰石的矿物学和地球化学特征,是深入开展相关研究的基础。本文对GEOROC数据库及其他文献报道的岩浆岩中磷灰石稀土元素数据进行了汇总整理和归纳分析,获得了不同类型岩石中磷灰石的矿物学和稀土元素组成特征。结合多元统计分析方法,深入分析不同类型岩浆岩和花岗岩中磷灰石的稀土元素变化规律。计算结果显示,不同类型岩石中磷灰石的La元素、Eu/Eu^*和Yb含量之间存在明显差异,推断综合利用La含量与(Eu/Eu^*)/Yb值特征可以有效区分形成于不同岩浆岩的磷灰石。本文的研究表明,磷灰石在示踪岩浆源区和岩石成因方面具有独特优势,综合运用磷灰石产状、共生矿物组合、微量元素及同位素组成等分析可以为岩浆岩成因研究提供全面信息。