The anaerobic digestion technology has been in existence for centuries and its underlying theory established for decades. It is considered a useful technology for the generation of renewable energy, and provides means to alleviate problems associated with low access to energy. However, a great deal of current research is targeted towards the optimization of this technology under diverse digestion process conditions. This review presents an in-depth analysis of the chemistry of anaerobic digestion and discusses how process chemistry can be used to optimize system performance through identification of methods that can accelerate syntrophic interactions of different microorganisms for improved methanogenic reactions. Recent advances in addition to old research are discussed in order to offer a general but comprehensive synopsis of accumulated knowledge in the theory of anaerobic digestion, as well as an overview of previous research and future directions and opportunities of the AD technology. Achieving a sustainable energy system requires comprehensive reforms in not just economic, social and policy aspects, but also in all technical aspects, which represents one of the most crucial future investments for anaerobic digestion systems.

There is a growing body of research that recognizes the potentials of biochar application in agricultural production systems. However, little is known about the effects of biochar, especially hydrochar, on production of containerized seedlings under nursery conditions. This study aimed to test the effects of hydrochar application on growth, quality, nutrient and heavy metal contents, and mycorrhizal association of containerized pine seedlings. The hydrochar used in this study was produced through hydrothermal carbonization of paper mill biosludge at 200 °C. Two forms of hydrochar (powder and pellet) were mixed with peat at ratios of 10% and 20% (v/v) under three levels of applied commercial fertilizer (nil, half and full rates). Application of hydrochar had positive or neutral effects on shoot biomass and stem diameter compared with control seedlings (without hydrochar) under tested fertilizer levels. Analysis of the natural logarithmic response ratios (LnRR) of quality index and nutrient and heavy metal uptake revealed that application of 20% (v/v) hydrochar powder or pellet with 50% fertilizer resulted in same quality pine seedlings with similar heavy metal (Cu, Ni, Pb, Zn and Cr) and nutrient (P, K, Ca and Mg) contents as untreated seedlings supplied with 100% fertilizer. Colonization percentage by ectomycorrhizae significantly increased when either forms of hydrochar were applied at a rate of 20% under unfertilized condition. The results of this study implied that application of proper rates of hydrochar from biosludge with adjusted levels of liquid fertilizer may reduce fertilizer requirements in pine nurseries.

Hydrothermal carbonization (HTC) has been seen as a potentially beneficial process for converting wet biomass into value-added products. It is, however, necessary to overcome the challenges associated with handling the powdered form of hydrochar—a solid product of the HTC process—by controlling the formation of dust and facilitating smoother transportation and distribution in a potentially wide marketplace. In this paper, the authors investigate the environmental consequences of different alternatives for using hydrochar pellets produced from mixed sludges from pulp and paper mills in Sweden, using the environmental life cycle assessment (E-LCA). Two scenarios for possible end-uses of hydrochar in combined heat and power (CHP) plants as a source of energy (heat and electricity) were assessed. In these scenarios, hydrochar pellets were assumed to be combusted in CHP plants, thereby avoiding the use of combustible solid wastes (Scenario A) and coal (Scenario B), respectively, to recover energy in the form of electricity and heat. The environmental damages to Human Health, Ecosystem Quality, Climate Change, and Resources are evaluated based on 1 tonne of dry sludge as the functional unit. The results from this analysis illustrate that Scenario B, in which hydrochar replaces coal, offers the greatest reduction in all the environmental damage characterizations, except the Resources category. The displacement of energy-based coal due to hydrochar combustion contributed most significantly to the environmental damages wrought by the system—ranging from 52% in Resources to 93% in Ecosystem Quality. Overall, the results highlight that the application of hydrochar pellets for energy recovery to offset waste- and coal-based energy sources has great environmental benefits. The favorability of sludge hydrochar over solid wastes as fuel for CHP plants may be counter-intuitive at first, since HTC is an energy-intensive process, but when accounting for the necessity of dependence on imports of wastes for instance, the hydrochar pellet may well emerge as a good option for CHPs in Sweden.