Alkaline anion exchange membranes (AAEMs) are an enabling component for next-generation electrochemical devices, including alkaline fuel cells, water and CO₂ electrolyzers, and flow batteries. While commercial systems, notably fuel cells, have traditionally relied on proton-exchange membranes, hydroxide-ion conducting AAEMs hold promise as a method to reduce cost-per-device by enabling the use of non-platinum group electrodes and cell components. AAEMs have undergone significant material development over the past two decades; however, challenges remain in the areas of durability, water management, high temperature performance, and selectivity. In this review, we survey crosslinking as a tool capable of tuning AAEM properties. While crosslinking implementations vary, they generally result in reduced water uptake and increased transport selectivity and alkaline stability. We survey synthetic methodologies for incorporating crosslinks during AAEM fabrication and highlight necessary precautions for each approach.

We are carrying out a multidisciplinary multi-institutional program to develop the scientific and technical basis for inertial fusion energy (IFE) based on laser drivers and direct-drive targets. The key components are developed as an integrated system, linking the science, technology, and final application of a 1000-MWe pure-fusion power plant. The science and technologies developed here are flexible enough to be applied to other size systems. The scientific justification for this work is a family of target designs (simulations) that show that direct drive has the potential to provide the high gains needed for a pure-fusion power plant. Two competing lasers are under development: the diode-pumped solid-state laser (DPPSL) and the electron-beam-pumped krypton fluoride (KrF) gas laser. This paper will present the current state of the art in the target designs and lasers, as well as the other IFE technologies required for energy, including final optics (grazing incidence and dielectrics), chambers, and target fabrication, injection, and tracking technologies. All of these are applicable to both laser systems and to other laser IFE-based concepts. However, in some of the higher performance target designs, the DPPSL will require more energy to reach the same yield as with the KrF laser.

Molecular dynamics simulations and umbrella sampling free energy calculations are used to examine the thermodynamics, energetics, and structural fluctuations that accompany the transfer of a small hydrophilic ion (Cl⁻) across the water/nitrobenzene interface. By examining several constrained interface structures, we isolate the energetic costs of interfacial deformation and co-transfer of hydration waters during the ion transfer. The process is monitored using both energy-based solvation coordinates and a geometric coordinate recently introduced by Morita and co-workers to describe surface fluctuations. Our simulations show that these coordinates provide a complimentary description of the water surface fluctuations during the transfer and are necessary for elucidating the mechanism of the ion transfer.