A flexible and portable triboelectric nanogenerator (TENG) based on electrospun polyvinylidene fluoride (PVDF) doped with copper oxide (CuO) nanoparticles (NPs, 2, 4, 6, 8, and 10 wt.-% w.r.t. PVDF content) was fabricated. The structural and crystalline properties of the as-prepared PVDF-CuO composite membranes were characterized using SEM, FTIR, and XRD. To fabricate the TENG device, the PVDF-CuO was considered a tribo-negative film and the polyurethane (PU) a counter-positive film. The output voltage of the TENG was analyzed using a custom-made dynamic pressure setup, under a constant load of 1.0 kgf and 1.0 Hz frequency. The neat PVDF/PU showed only 1.7 V, which further increased up to 7.5 V when increasing the CuO contents from 2 to 8 wt.-%. A decrease in output voltage to 3.9 V was observed for 10 wt.-% CuO. Based on the above results, further measurements were carried out using the optimal sample (8 wt.-% CuO). Its output voltage performance was evaluated as a function of varying load (1 to 3 kgf) and frequency (0.1 to 1.0 Hz) conditions. Finally, the optimized device was demonstrated in real-time wearable sensor applications, such as human motion and health-monitoring applications (respiration and heart rate).

Flexible electrospun fiber-based piezoelectric nanogenerator (PENG) has attracted a lot of interest due to its ability of generating electrical energy from mechanical energy sources. The present work aims to improve the piezoelectric output of PENG devices based on electrospun polyvinylidene fluoride (PVDF) doped with nickel oxide nanoparticles (NiO NPs) in different concentrations (2, 4, 6, 8 and 10 wt.-%). Crystalline phase changes and β-crystalline content in electrospun fibers were evaluated using XRD and FTIR-ATR, respectively. Surface morphology and surface roughness of the electrospun fibers were observed using FE-SEM and AFM, respectively. The hydrophobic nature of the fibers was analyzed using a wettability test. PENG output voltage and short-circuit current performance of neat PVDF and PVDF doped with NiO (PN) composite electrospun fibers were calculated using a customized variable-pressure setup with an optimized force of 1.0 kgf and 1.0 Hz frequency. Neat PVDF-based PENG exhibited only 1.7 V and 0.7 μA, whereas, PVDF doped with 6 wt.-% NiO NP (PN-6) based PENG generated a high output voltage of 5.5 V and 1.83 μA current. The optimized PN-6 PENG device is demonstrated for use in wearable devices towards identifying certain body movements like tapping, wrist movement, walking and running.

CaSiO3 is one of the bioactive calcium silicate materials and known as wollastonite. Herewith, for the first time, we have employed sol–gel combustion method to synthesize Ag-doped CaSiO3 using glycine as a fuel. The sintered powders were characterized by ATR-FTIR, XRD and SEM analysis which proved the existence of characteristic functional groups, pure phase formation and flakes, dense morphology with agglomeration, respectively. TEM-SAED analysis confirms that particles are in nano regime with crystalline nature. SBF immersion reveals that pure and Ag-doped CaSiO3 exhibit the good apatite layer formation for 7 and 14 days. Pure and Ag-doped CaSiO3 were evaluated for their antibacterial behaviour against E. coli and S. aureus which reflects the excellent inhibition of microorganisms. MTT assay proves that the prepared 5 wt-% of Ag-doped CaSiO3 exhibits the excellent cellular metabolic activity with MG-63 cells at different concentrations (50–250 μg ml−1) for 24–48 h.