The research aimed at the composition optimization for diamond-SiC-Si composites. The effect of a porous diamond workpiece was studied on the properties (porosity, density, modulus of elasticity, phase composition) of the product of its siliconization with molten silicon. The lowest porosity and highest modulus of elasticity were observed in the case of using mixed matrices with the maximum size of diamond grains of 250/200 μm for siliconization. The best results in terms of the sound speed (16,600 m/s) and elasticity modulus (860 GPa) were achieved by microwave processing of a composite containing detonation nanodiamonds.
The work proposes the use of aluminum oxide-based ceramic objects with a TPMS-Q-surface geometry as elements of armor structures. The samples were produced using the SLA-DLP 3D printing method. The main properties of the sample were determined using physical-chemical analysis methods: apparent density ρap = 3.6 g/cm3, open porosity Popn = 8.5%, microhardness Hµ = 15.3 GPa, water absorption W = 2.4%, elastic modulus E = 405 GPa. The Stiglich criterion M = 1.72 EPa2·m3/kg, and the Shevchenko criterion K = 0.8.
— Xerogels in the ZrO2(Y2O3)–Al2O3system are obtained by the coprecipitation method followed by a low-temperature treatment at –25°C for 24 h. The physicochemical properties of the powders...
Xerogels in the ZrO2–Y2O3–CeO2 system are obtained by coprecipitation. The influence of the synthesis method on the acid-base xerogel surface properties are studied. The sinuous dependence of the Lewis and Brønsted site content on the particle surface on the conditioning time of precipitates in the mother liquor and the presence of subsequent low-temperature processing is established. The relationship is established between the resulting ceramics properties, precipitate processing conditions, and the functional xerogel structure.
The possibility of synthesizing a new hybrid phosphor CSSC (mixture of 0.5 CaSrSiO4:Eu2+: 0.29 Ca6Sr4Si6O21Cl2:Eu2+: 0.21 Ca10Si6O21Cl2:Eu2+) using a one-step microwave synthesis method is demonstrated. The concentrations of europium and calcium in the synthesized phosphors were optimized at 1 and 10 mol. %, respectively, to achieve maximum brightness and color rendering index. The optimal conditions for the synthesis of phosphors in a microwave furnace were determined as 750 °C for 10 min. The resulting phosphor exhibited a wide luminescence spectrum that covered the entire visible region, resulting in a high color rendering index and a warm white luminescence when used as a light source. It is shown that the sol–gel method for preparing the charge mixture for the new phosphor allows for a 35% higher luminescence brightness compared to the solid-phase method, due to a more uniform distribution of the activator.