Environmental pollution, particularly from heavy metals and toxic elements, poses a significant threat to both human health and ecological systems. While various remediation technologies exist, there is an urgent need for cost-effective and sustainable solutions. Biochar, a carbon-rich product derived from the pyrolysis of organic matter, has emerged as a promising material for environmental remediation. However, its pristine form has limitations, such as low adsorption capacities, a relatively narrow range of pH adaptability which can limit its effectiveness in diverse environmental conditions, and a tendency to lose adsorption capacity rapidly in the presence of competing ions or organic matters. This review aims to explore the burgeoning field of nanomaterial-modified biochar, which seeks to overcome the limitations of pristine biochar. By incorporating nanomaterials, the adsorptive and reactive properties of biochar can be significantly enhanced. Such modifications, especially biochar supported with metal nanoparticles (biochar-MNPs), have shown promise in various applications, including the removal of heavy metals, organic contaminants, and other inorganic pollutants from aqueous environments, soil, and air. This review provides a comprehensive overview of the synthesis techniques, characterization methods, and applications of biochar-MNPs, as well as discusses their underlying mechanisms for contaminant removal. It also offers insights into the advantages and challenges of using nanomaterial-modified biochar for environmental remediation and suggests directions for future research.

Kraft lignin (KL) was thermally treated at 500 to 1000 °C in an inert atmosphere. Carbon nanostructure parameters of thermally treated KL in terms of amorphous carbon fraction, aromaticity, and carbon nanocrystallites lateral size (L_a), thickness (L_c), and interlayer space (d₀₀₂) were analyzed quantitatively using X-ray diffraction, Raman spectroscopy, and high-resolution transmission electron microscopy. Experimental results indicated that increasing temperature reduced amorphous carbon but increased aromaticity in thermally treated KL materials. The L_c value of thermally treated KL materials averaged 0.85 nm and did not change with temperature. The d₀₀₂ value decreased from 3.56 Å at 500 °C to 3.49 Å at 1000 °C. The L_a value increased from 0.7 to 1.4 nm as temperature increased from 500 to 1000 °C. A nanostructure model was proposed to describe thermally treated KL under 1000 °C. The thermal stability of heat treated KL increased with temperature rising from 500 to 800 °C.

Lignin graphene oxide was oxidized after Kraft lignin was graphitized by thermal catalytic conversion. The reduced lignin graphene oxide was derived from lignin graphene oxide through thermal reduction treatment. These Kraft lignin, lignin graphite, lignin graphene oxide, and reduced lignin graphene oxide were characterized by scanning electron microscopy, raman microscopy, high-resolution transmission electron microscopy, X-ray diffraction, Fourier transform infrared spectroscopy, atomic force microscopy and thermogravimetric analysis. The results showed lignin graphite converted from Kraft lignin had fewer layers with smaller lateral size than natural graphite. Moreover, lignin graphene oxide was successfully produced from lignin graphite by an oxidation reaction with an hour-long reaction time, which has remarkably shorter reaction time than that of graphene oxide made from natural graphite. Meanwhile, this lignin-derived graphene oxide had the same XRD, FTIR and Raman peaks as graphene oxide oxidized from natural graphite. The SEM, TEM, and AFM images showed that this lignin graphene oxide with 1–3 average layers has a smaller lateral size than that of graphene oxide made from natural graphite. Moreover, the lignin graphene oxide can be reduced to reduced lignin graphene oxide to fabricate graphene-based aerogel, wire, and film for some potential applications.

A novel process is developed for high-volume production of low-cost graphene materials from any solid carbon resources, especially biomass sources. Few-layer graphene materials from solid carbon resources are produced through a molecular cracking and welding (MCW) method. The MCW technique is a single step process with two stages, i.e., graphene-encapsulated core–shell nanoparticles are first formed by catalytic thermal treatment of solid carbon materials. Then in the second stage these core–shell structures are opened by ‘cracking molecules’, and the cracked graphene shells are self-welded and reconstructed to form high quality multilayer graphene materials at a heating temperature with selected welding reagent gases. This novel graphene material with super hydrophobic properties can be used to filter water from crude oil emulsions in the petroleum industry.

Kraft lignin was catalytically graphitized to graphene-based nanostructures at 1000 °C under argon atmosphere with four iron catalysts, iron(III) nitrate (Fe-N); iron(II) chloride (Fe-Cl₂); iron(III) chloride (Fe-Cl₃); and iron(II) sulfate (Fe-S). The catalytic decomposition process of iron-promoted lignin materials was examined using thermalgravimetric analysis and temperature-programmed decomposition methods. The crystal structure, morphology and surface area of produced materials were characterized by means of X-ray diffraction, Raman, scanning electron microscopy, high resolution transmission electron microscopy and N₂ adsorption−desorption techniques. Experimental results indicated that iron nitrate catalyst had better iron dispersion three other iron salts. Iron nitrate was the most active catalyst among four iron salts. The low activity of iron in iron chloride-promoted samples was because the residual chlorine over iron surfaces prevent iron interaction with lignin functional groups.